Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate
In the title compound, [Cu(SO4)(C10H9NO2)2]·2H2O, the CuII ion is chelated by two (2-quinolyl)methanediol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal–bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial s...
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International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808001980 |
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doaj-b2b0dde89a22401e8e3b2a5c321343752020-11-25T01:57:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m394m39410.1107/S1600536808001980Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrateAbilio J. F. N. SobralAna Matos BejaManuela Ramos SilvaJoana A. SilvaNuno D. MartinsIn the title compound, [Cu(SO4)(C10H9NO2)2]·2H2O, the CuII ion is chelated by two (2-quinolyl)methanediol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal–bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial sites. The dihedral angle between the two essentially planar quinoline ring systems is 45.02 (9)°. In the crystal structure, an extensive O—H...O hydrogen-bonding network forms layers parallel to the ab plane.http://scripts.iucr.org/cgi-bin/paper?S1600536808001980 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Abilio J. F. N. Sobral Ana Matos Beja Manuela Ramos Silva Joana A. Silva Nuno D. Martins |
| spellingShingle |
Abilio J. F. N. Sobral Ana Matos Beja Manuela Ramos Silva Joana A. Silva Nuno D. Martins Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate Acta Crystallographica Section E |
| author_facet |
Abilio J. F. N. Sobral Ana Matos Beja Manuela Ramos Silva Joana A. Silva Nuno D. Martins |
| author_sort |
Abilio J. F. N. Sobral |
| title |
Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate |
| title_short |
Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate |
| title_full |
Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate |
| title_fullStr |
Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate |
| title_full_unstemmed |
Bis[(2-quinolyl)methanediol-κ2N,O](sulfato-κO)copper(II) dihydrate |
| title_sort |
bis[(2-quinolyl)methanediol-κ2n,o](sulfato-κo)copper(ii) dihydrate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2008-02-01 |
| description |
In the title compound, [Cu(SO4)(C10H9NO2)2]·2H2O, the CuII ion is chelated by two (2-quinolyl)methanediol ligands and coordinated by a monodentate sulfate ligand in a distorted trigonal–bipyramidal environment, with O atoms occupying the equatorial sites and N atoms in the axial sites. The dihedral angle between the two essentially planar quinoline ring systems is 45.02 (9)°. In the crystal structure, an extensive O—H...O hydrogen-bonding network forms layers parallel to the ab plane. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808001980 |
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