Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor

An aqueous solution was successfully prepared using a low-molecular-weight chitosan oligomer and FITC, and its structural and fluorescent properties were observed by using 1H NMR, 13C NMR, FT-IR, XRD, UV-Vis, and PL spectrometry. Its application as a metal ion sensor was also evaluated. The fluoresc...

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Main Authors: Hun Min Lee, Min Hee Kim, Young Il Yoon, Won Ho Park
Format: Article
Language:English
Published: MDPI AG 2017-04-01
Series:Marine Drugs
Subjects:
Online Access:http://www.mdpi.com/1660-3397/15/4/105
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spelling doaj-b12adfa52d934cc2ba49ed1a27c79a7c2020-11-24T20:57:07ZengMDPI AGMarine Drugs1660-33972017-04-0115410510.3390/md15040105md15040105Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion SensorHun Min Lee0Min Hee Kim1Young Il Yoon2Won Ho Park3Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University, Daejeon 34134, KoreaDepartment of Advanced Organic Materials and Textile System Engineering, Chungnam National University, Daejeon 34134, KoreaLaboratory of Molecular Imaging and Nanomedicine (LOMIN), National Institute of Biomedical Imaging and Bioengineering (NIBIB), National Institutes of Health (NIH), Bethesda, MD 20892, USADepartment of Advanced Organic Materials and Textile System Engineering, Chungnam National University, Daejeon 34134, KoreaAn aqueous solution was successfully prepared using a low-molecular-weight chitosan oligomer and FITC, and its structural and fluorescent properties were observed by using 1H NMR, 13C NMR, FT-IR, XRD, UV-Vis, and PL spectrometry. Its application as a metal ion sensor was also evaluated. The fluorescence in the water-soluble chitosan oligomer was a result of the carbamato anion (NHCOO-), and a synthesized FITC-labeled chitosan oligomer exhibited an effective detection effect for copper ion as well as energy transfer by the ion near FITC that caused a fluorescence decrease (quenching). The chitosan oligomer was confirmed to be applicable as a selective and sensitive colorimetric sensor to detect Cu2+.http://www.mdpi.com/1660-3397/15/4/105chitosan oligomerfluorescent propertymetal ion sensor
collection DOAJ
language English
format Article
sources DOAJ
author Hun Min Lee
Min Hee Kim
Young Il Yoon
Won Ho Park
spellingShingle Hun Min Lee
Min Hee Kim
Young Il Yoon
Won Ho Park
Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor
Marine Drugs
chitosan oligomer
fluorescent property
metal ion sensor
author_facet Hun Min Lee
Min Hee Kim
Young Il Yoon
Won Ho Park
author_sort Hun Min Lee
title Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor
title_short Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor
title_full Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor
title_fullStr Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor
title_full_unstemmed Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor
title_sort fluorescent property of chitosan oligomer and its application as a metal ion sensor
publisher MDPI AG
series Marine Drugs
issn 1660-3397
publishDate 2017-04-01
description An aqueous solution was successfully prepared using a low-molecular-weight chitosan oligomer and FITC, and its structural and fluorescent properties were observed by using 1H NMR, 13C NMR, FT-IR, XRD, UV-Vis, and PL spectrometry. Its application as a metal ion sensor was also evaluated. The fluorescence in the water-soluble chitosan oligomer was a result of the carbamato anion (NHCOO-), and a synthesized FITC-labeled chitosan oligomer exhibited an effective detection effect for copper ion as well as energy transfer by the ion near FITC that caused a fluorescence decrease (quenching). The chitosan oligomer was confirmed to be applicable as a selective and sensitive colorimetric sensor to detect Cu2+.
topic chitosan oligomer
fluorescent property
metal ion sensor
url http://www.mdpi.com/1660-3397/15/4/105
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AT youngilyoon fluorescentpropertyofchitosanoligomeranditsapplicationasametalionsensor
AT wonhopark fluorescentpropertyofchitosanoligomeranditsapplicationasametalionsensor
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