Fluorescent Property of Chitosan Oligomer and Its Application as a Metal Ion Sensor

An aqueous solution was successfully prepared using a low-molecular-weight chitosan oligomer and FITC, and its structural and fluorescent properties were observed by using 1H NMR, 13C NMR, FT-IR, XRD, UV-Vis, and PL spectrometry. Its application as a metal ion sensor was also evaluated. The fluoresc...

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Bibliographic Details
Main Authors: Hun Min Lee, Min Hee Kim, Young Il Yoon, Won Ho Park
Format: Article
Language:English
Published: MDPI AG 2017-04-01
Series:Marine Drugs
Subjects:
Online Access:http://www.mdpi.com/1660-3397/15/4/105
Description
Summary:An aqueous solution was successfully prepared using a low-molecular-weight chitosan oligomer and FITC, and its structural and fluorescent properties were observed by using 1H NMR, 13C NMR, FT-IR, XRD, UV-Vis, and PL spectrometry. Its application as a metal ion sensor was also evaluated. The fluorescence in the water-soluble chitosan oligomer was a result of the carbamato anion (NHCOO-), and a synthesized FITC-labeled chitosan oligomer exhibited an effective detection effect for copper ion as well as energy transfer by the ion near FITC that caused a fluorescence decrease (quenching). The chitosan oligomer was confirmed to be applicable as a selective and sensitive colorimetric sensor to detect Cu2+.
ISSN:1660-3397