Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

1,1-diborylalkanes are useful building blocks in synthetic chemistry. Here, the authors present a highly chemo- and regioselective Ni-catalyzed reaction for the synthesis of 1,1-diborylalkanes from a wide variety of readily available terminal alkenes.

Bibliographic Details
Main Authors: Lei Li, Tianjun Gong, Xi Lu, Bin Xiao, Yao Fu
Format: Article
Language:English
Published: Nature Publishing Group 2017-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-00363-4
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spelling doaj-b10ddbbd1fc44a218ee4363da34845fa2021-05-11T07:55:25ZengNature Publishing GroupNature Communications2041-17232017-08-01811710.1038/s41467-017-00363-4Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenesLei Li0Tianjun Gong1Xi Lu2Bin Xiao3Yao Fu4Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, University of Science and Technology of China1,1-diborylalkanes are useful building blocks in synthetic chemistry. Here, the authors present a highly chemo- and regioselective Ni-catalyzed reaction for the synthesis of 1,1-diborylalkanes from a wide variety of readily available terminal alkenes.https://doi.org/10.1038/s41467-017-00363-4
collection DOAJ
language English
format Article
sources DOAJ
author Lei Li
Tianjun Gong
Xi Lu
Bin Xiao
Yao Fu
spellingShingle Lei Li
Tianjun Gong
Xi Lu
Bin Xiao
Yao Fu
Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
Nature Communications
author_facet Lei Li
Tianjun Gong
Xi Lu
Bin Xiao
Yao Fu
author_sort Lei Li
title Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
title_short Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
title_full Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
title_fullStr Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
title_full_unstemmed Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
title_sort nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2017-08-01
description 1,1-diborylalkanes are useful building blocks in synthetic chemistry. Here, the authors present a highly chemo- and regioselective Ni-catalyzed reaction for the synthesis of 1,1-diborylalkanes from a wide variety of readily available terminal alkenes.
url https://doi.org/10.1038/s41467-017-00363-4
work_keys_str_mv AT leili nickelcatalyzedsynthesisof11diborylalkanesfromterminalalkenes
AT tianjungong nickelcatalyzedsynthesisof11diborylalkanesfromterminalalkenes
AT xilu nickelcatalyzedsynthesisof11diborylalkanesfromterminalalkenes
AT binxiao nickelcatalyzedsynthesisof11diborylalkanesfromterminalalkenes
AT yaofu nickelcatalyzedsynthesisof11diborylalkanesfromterminalalkenes
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