{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)

{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)

In the title dinuclear complex, [CuGd(C20H22N2O4)(NO3)3], the CuII ion is located in the inner N2O2 cavity of the Schiff base ligand and adopts a distorted square-planar geometry. The GdIII ion is ten-coordinate being bound to ten O atoms, four from the Schiff base ligand and six from three bidentat...

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Bibliographic Details
Main Authors: Christopher Chan, Xiaoping Yang, Richard A. Jones, Bradley J. Holliday, Julie M. Stanley
Format: Article
Language:English
Published: International Union of Crystallography 2010-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810014716
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spelling doaj-b0ebbcf4fe6247ae83f610d59e01a87e2020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-05-01665m576m57710.1107/S1600536810014716{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)Christopher ChanXiaoping YangRichard A. JonesBradley J. HollidayJulie M. StanleyIn the title dinuclear complex, [CuGd(C20H22N2O4)(NO3)3], the CuII ion is located in the inner N2O2 cavity of the Schiff base ligand and adopts a distorted square-planar geometry. The GdIII ion is ten-coordinate being bound to ten O atoms, four from the Schiff base ligand and six from three bidentate nitrate anions. The CuII and GdIII ions are linked by two phenolate O atoms of the Schiff base ligand, with a separation of 3.5185 (9) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536810014716
collection DOAJ
language English
format Article
sources DOAJ
author Christopher Chan
Xiaoping Yang
Richard A. Jones
Bradley J. Holliday
Julie M. Stanley
spellingShingle Christopher Chan
Xiaoping Yang
Richard A. Jones
Bradley J. Holliday
Julie M. Stanley
{μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)
Acta Crystallographica Section E
author_facet Christopher Chan
Xiaoping Yang
Richard A. Jones
Bradley J. Holliday
Julie M. Stanley
author_sort Christopher Chan
title {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)
title_short {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)
title_full {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)
title_fullStr {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)
title_full_unstemmed {μ-6,6′-Dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8O6,O1,O1′,O6′:O1,N,N′,O1′}tris(nitrato-1κ2O,O′)copper(II)gadolinium(III)
title_sort {μ-6,6′-dimethoxy-2,2′-[butane-1,4-diylbis(nitrilomethylidyne)]diphenolato-1:2κ8o6,o1,o1′,o6′:o1,n,n′,o1′}tris(nitrato-1κ2o,o′)copper(ii)gadolinium(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-05-01
description In the title dinuclear complex, [CuGd(C20H22N2O4)(NO3)3], the CuII ion is located in the inner N2O2 cavity of the Schiff base ligand and adopts a distorted square-planar geometry. The GdIII ion is ten-coordinate being bound to ten O atoms, four from the Schiff base ligand and six from three bidentate nitrate anions. The CuII and GdIII ions are linked by two phenolate O atoms of the Schiff base ligand, with a separation of 3.5185 (9) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810014716
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