Gold-catalyzed propargylic substitutions: Scope and synthetic developments

Gold-catalyzed propargylic substitutions: Scope and synthetic developments

This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.

Bibliographic Details
Main Authors: Olivier Debleds, Eric Gayon, Emmanuel Vrancken, Jean-Marc Campagne
Format: Article
Language:English
Published: Beilstein-Institut 2011-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
direct substitutions
gold
isoxazolines
propargylic substitutions
Online Access:https://doi.org/10.3762/bjoc.7.99
Description
Summary:This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.
ISSN:1860-5397

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