Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole Systems
A novel class of anion receptors with with C-H···X- hydrogen bonding is introduced and demonstrated for Cl-, Br-, NO3- and HSO4- recognition. Cyclic voltammetry revealed that novel ferrocenylimidazolium salts, syntheses of which are briefly described, selectively complex and electrochemical...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2002-12-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | http://www.mdpi.com/1420-3049/7/12/861/ |
| id |
doaj-b017634a8e0743a081adda87e4602811 |
|---|---|
| record_format |
Article |
| spelling |
doaj-b017634a8e0743a081adda87e46028112020-11-24T21:06:03ZengMDPI AGMolecules1420-30492002-12-0171286186610.3390/71200861Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole SystemsAnthony M. KennedyJoshua HowarthJean-Luc ThomasA novel class of anion receptors with with C-H···X- hydrogen bonding is introduced and demonstrated for Cl-, Br-, NO3- and HSO4- recognition. Cyclic voltammetry revealed that novel ferrocenylimidazolium salts, syntheses of which are briefly described, selectively complex and electrochemically recognise guest anions. Futhermore, proton NMR spectroscopy indicated the formation of 1:2 stoichiometric complexes with Cl-, Br and I- and 1:1 stoichiometric complexes with NO3- and HSO4-.http://www.mdpi.com/1420-3049/7/12/861/Ferrocenylimidazolium saltsanion receptors1H-NMR titrationscyclovoltammetryrecognition |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Anthony M. Kennedy Joshua Howarth Jean-Luc Thomas |
| spellingShingle |
Anthony M. Kennedy Joshua Howarth Jean-Luc Thomas Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole Systems Molecules Ferrocenylimidazolium salts anion receptors 1H-NMR titrations cyclovoltammetry recognition |
| author_facet |
Anthony M. Kennedy Joshua Howarth Jean-Luc Thomas |
| author_sort |
Anthony M. Kennedy |
| title |
Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole Systems |
| title_short |
Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole Systems |
| title_full |
Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole Systems |
| title_fullStr |
Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole Systems |
| title_full_unstemmed |
Electrochemical Anion Recognition By Novel Ferrocenyl Imidazole Systems |
| title_sort |
electrochemical anion recognition by novel ferrocenyl imidazole systems |
| publisher |
MDPI AG |
| series |
Molecules |
| issn |
1420-3049 |
| publishDate |
2002-12-01 |
| description |
A novel class of anion receptors with with C-H···X- hydrogen bonding is introduced and demonstrated for Cl-, Br-, NO3- and HSO4- recognition. Cyclic voltammetry revealed that novel ferrocenylimidazolium salts, syntheses of which are briefly described, selectively complex and electrochemically recognise guest anions. Futhermore, proton NMR spectroscopy indicated the formation of 1:2 stoichiometric complexes with Cl-, Br and I- and 1:1 stoichiometric complexes with NO3- and HSO4-. |
| topic |
Ferrocenylimidazolium salts anion receptors 1H-NMR titrations cyclovoltammetry recognition |
| url |
http://www.mdpi.com/1420-3049/7/12/861/ |
| work_keys_str_mv |
AT anthonymkennedy electrochemicalanionrecognitionbynovelferrocenylimidazolesystems AT joshuahowarth electrochemicalanionrecognitionbynovelferrocenylimidazolesystems AT jeanlucthomas electrochemicalanionrecognitionbynovelferrocenylimidazolesystems |
| _version_ |
1716766931090931712 |