Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate
In the title compound, C6H16N+·C15H13N2O2S2−, the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81...
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International Union of Crystallography
2008-01-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807067037 |
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doaj-afc4d2259e0043e7b7e8cd6f4f26f1112020-11-25T02:31:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641o339o33910.1107/S1600536807067037Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidateAjay K. SrivastavaN. K. SinghAnuraag ShrivastavR. K. SharmaMamata SinghIn the title compound, C6H16N+·C15H13N2O2S2−, the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The molecular conformation is stabilized by intramolecular O—H...O and N—H...S hydrogen bonds, while intermolecular N—H...O, N—H...N and weak C—H...O interactions help to stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536807067037 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ajay K. Srivastava N. K. Singh Anuraag Shrivastav R. K. Sharma Mamata Singh |
spellingShingle |
Ajay K. Srivastava N. K. Singh Anuraag Shrivastav R. K. Sharma Mamata Singh Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate Acta Crystallographica Section E |
author_facet |
Ajay K. Srivastava N. K. Singh Anuraag Shrivastav R. K. Sharma Mamata Singh |
author_sort |
Ajay K. Srivastava |
title |
Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_short |
Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_full |
Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_fullStr |
Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_full_unstemmed |
Triethylammonium N′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
title_sort |
triethylammonium n′-(benzylsulfanylthiocarbonyl)-2-hydroxybenzohydrazidate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2008-01-01 |
description |
In the title compound, C6H16N+·C15H13N2O2S2−, the thione S atom is in a cis configuration with respect to the phenyl and benzene rings, while it adopts a trans configuration with respect to the carbonyl group. The dihedral angle between the benzene and phenyl rings is 78.81 (2)°. The molecular conformation is stabilized by intramolecular O—H...O and N—H...S hydrogen bonds, while intermolecular N—H...O, N—H...N and weak C—H...O interactions help to stabilize the crystal structure. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536807067037 |
work_keys_str_mv |
AT ajayksrivastava triethylammoniumn8242benzylsulfanylthiocarbonyl2hydroxybenzohydrazidate AT nksingh triethylammoniumn8242benzylsulfanylthiocarbonyl2hydroxybenzohydrazidate AT anuraagshrivastav triethylammoniumn8242benzylsulfanylthiocarbonyl2hydroxybenzohydrazidate AT rksharma triethylammoniumn8242benzylsulfanylthiocarbonyl2hydroxybenzohydrazidate AT mamatasingh triethylammoniumn8242benzylsulfanylthiocarbonyl2hydroxybenzohydrazidate |
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1724824742144245760 |