(Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)

(Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)

The UVI atom in the title complex, [U(C17H15N3O2S)O2(C2H6OS)], exists within a distorted pentagonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the pentagonal plane is defined by the N...

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Main Authors: Seik Weng Ng, Reza Takjoo, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812003789
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spelling doaj-af82bd1044bf4c3da3afb0ec351f83d02020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m244m24510.1107/S1600536812003789(Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)Seik Weng NgReza TakjooEdward R. T. TiekinkThe UVI atom in the title complex, [U(C17H15N3O2S)O2(C2H6OS)], exists within a distorted pentagonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the dimethyl sulfoxide molecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H...O interactions. The azomethine C=N atoms and ethylthiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio.http://scripts.iucr.org/cgi-bin/paper?S1600536812003789
collection DOAJ
language English
format Article
sources DOAJ
author Seik Weng Ng
Reza Takjoo
Edward R. T. Tiekink
spellingShingle Seik Weng Ng
Reza Takjoo
Edward R. T. Tiekink
(Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)
Acta Crystallographica Section E
author_facet Seik Weng Ng
Reza Takjoo
Edward R. T. Tiekink
author_sort Seik Weng Ng
title (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)
title_short (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)
title_full (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)
title_fullStr (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)
title_full_unstemmed (Dimethyl sulfoxide-κO)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κO)hydrazinylidene-κN2]methyl}iminomethyl)phenolato-κO]dioxidouranium(VI)
title_sort (dimethyl sulfoxide-κo)[2-({(ethylsulfanyl)[2-(2-oxidobenzylidene-κo)hydrazinylidene-κn2]methyl}iminomethyl)phenolato-κo]dioxidouranium(vi)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description The UVI atom in the title complex, [U(C17H15N3O2S)O2(C2H6OS)], exists within a distorted pentagonal–pyramidal geometry where the oxide atoms occupy axial positions [O—U—O = 177.84 (14)°] and the pentagonal plane is defined by the N2O2 atoms of the tetradentate Schiff base ligand and the O atom of the dimethyl sulfoxide molecule. In the crystal, centrosymmetric aggregates are formed via pairs of C—H...O interactions. The azomethine C=N atoms and ethylthiolyl group are disordered over two orientations in a 0.828 (3):0.172 (3) ratio.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812003789
work_keys_str_mv AT seikwengng dimethylsulfoxideamp954o2ethylsulfanyl22oxidobenzylideneamp954ohydrazinylideneamp954n2methyliminomethylphenolatoamp954odioxidouraniumvi
AT rezatakjoo dimethylsulfoxideamp954o2ethylsulfanyl22oxidobenzylideneamp954ohydrazinylideneamp954n2methyliminomethylphenolatoamp954odioxidouraniumvi
AT edwardrttiekink dimethylsulfoxideamp954o2ethylsulfanyl22oxidobenzylideneamp954ohydrazinylideneamp954n2methyliminomethylphenolatoamp954odioxidouraniumvi
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