Photoluminescence and concentration quenching of Pr3+ doped BaTa2O6 phosphor

The pure and Pr3+ doped TTB-BaTa2O6 phosphors were obtained by the solid state reaction method at 1 425 °C for 20hours. X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM) analyses confirmed a single phase of BaTa2O6up to 10 mol % Pr2O36. SEM analysis also shows that BaTa2O6 grain size de...

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Bibliographic Details
Main Authors: M. Ilhan, R. Samur, H. Demirer, F. Mindivan
Format: Article
Language:English
Published: Croatian Metallurgical Society 2015-04-01
Series:Metalurgija
Subjects:
TTB
Online Access:http://hrcak.srce.hr/file/190517
Description
Summary:The pure and Pr3+ doped TTB-BaTa2O6 phosphors were obtained by the solid state reaction method at 1 425 °C for 20hours. X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM) analyses confirmed a single phase of BaTa2O6up to 10 mol % Pr2O36. SEM analysis also shows that BaTa2O6 grain size decreased with the increasing Pr2O36 concentration.The chemical composition of Pr3+ doped BaTa2O6 structures was confirmed by Energy Dispersive Spectroscopy(EDS) analysis. BaTa2O6:Pr3+ phosphors exhibited on a strong red emission at 620,9 nm, a green emission at 548,3 nm and a red emission at 655,2 nm. Emission intensity increased with Pr3+ doping concentration up to 1,5 mol %, then decreased due to concentration quenching.
ISSN:0543-5846
1334-2576