Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate

Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate

The title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl− ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and another chloride ion to for...

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Bibliographic Details
Main Authors: Abdul-Razak H. Al-Sudani, Myasim Qasim Abdulridha, Benson M. Kariuki
Format: Article
Language:English
Published: International Union of Crystallography 2021-02-01
Series:IUCrData
Subjects:
crystal structure
cadmium
complex
quinoline
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314621001504
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spelling doaj-aecb6a5463834a06ae2b47f575deda432021-04-22T11:00:42ZengInternational Union of CrystallographyIUCrData2414-31462021-02-0162x21015010.1107/S2414314621001504hb4375Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvateAbdul-Razak H. Al-Sudani0Myasim Qasim Abdulridha1Benson M. Kariuki2Department of Chemistry, College of Science for Women, University of Baghdad, IraqDepartment of Chemistry, College of Science for Women, University of Baghdad, IraqSchool of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10, 3AT, UKThe title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl− ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and another chloride ion to form a distorted fac-CdN3Cl3 octahedron. The ethanol molecule is both an acceptor of an N—H...O and a donor of an O—H...Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed.http://scripts.iucr.org/cgi-bin/paper?S2414314621001504crystal structurecadmiumcomplexquinoline
collection DOAJ
language English
format Article
sources DOAJ
author Abdul-Razak H. Al-Sudani
Myasim Qasim Abdulridha
Benson M. Kariuki
spellingShingle Abdul-Razak H. Al-Sudani
Myasim Qasim Abdulridha
Benson M. Kariuki
Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
IUCrData
crystal structure
cadmium
complex
quinoline
author_facet Abdul-Razak H. Al-Sudani
Myasim Qasim Abdulridha
Benson M. Kariuki
author_sort Abdul-Razak H. Al-Sudani
title Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
title_short Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
title_full Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
title_fullStr Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
title_full_unstemmed Di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
title_sort di-μ-chlorido-bis(chlorido{8-[2-(dimethylamino)ethylamino]quinoline}cadmium) ethanol monosolvate
publisher International Union of Crystallography
series IUCrData
issn 2414-3146
publishDate 2021-02-01
description The title solvated bimetallic complex, [Cd2Cl4(C13H17N3)2]·C2H5OH, comprises two Cd2+ metal ions linked by a pair of μ2 Cl− ions. The coordination sphere around each Cd2+ ion is completed by three N atoms of a tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and another chloride ion to form a distorted fac-CdN3Cl3 octahedron. The ethanol molecule is both an acceptor of an N—H...O and a donor of an O—H...Cl hydrogen bonds to its adjacent complex unit. In the crystal, weak aromatic π–π stacking is observed.
topic crystal structure
cadmium
complex
quinoline
url http://scripts.iucr.org/cgi-bin/paper?S2414314621001504
work_keys_str_mv AT abdulrazakhalsudani dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate
AT myasimqasimabdulridha dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate
AT bensonmkariuki dimchloridobischlorido82dimethylaminoethylaminoquinolinecadmiumethanolmonosolvate
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