Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide

The structures of two azide containing imidazole derivatives are reported. Allylic azides are fairly reactive making them attractive starting compounds to convert into amides. The first, C8H12N6O2S, contains one azide group with an Nα—Nβ distance of 1.229 (2) Å and an Nβ—Nγ distance of 1.128 (2) Å....

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Main Authors:	Lorenzo M. Cruz, Raakiyah Y. Moore, Marcela Torres Gutierrez, Apsara K. Herath, Carl J. Lovely, Muhammed Yousufuddin
Format:	Article
Language:	English
Published:	International Union of Crystallography 2019-05-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	crystal structure imidazole nagelamide azide amide
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S205698901900519X

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record_format	Article
spelling	doaj-aebfe0be6a474a8d9086f441ddcf36152020-11-24T21:21:34ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902019-05-0175569569910.1107/S205698901900519Xzl2753Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamideLorenzo M. Cruz0Raakiyah Y. Moore1Marcela Torres Gutierrez2Apsara K. Herath3Carl J. Lovely4Muhammed Yousufuddin5Life and Health Sciences Department, University of North Texas at Dallas, 7400 University Hills Blvd, Dallas, TX 75241, USALife and Health Sciences Department, University of North Texas at Dallas, 7400 University Hills Blvd, Dallas, TX 75241, USALife and Health Sciences Department, University of North Texas at Dallas, 7400 University Hills Blvd, Dallas, TX 75241, USADepartment of Chemistry and Biochemistry, University of Texas at Arlington, 700 Planetarium Pl., Arlington, TX 76019, USADepartment of Chemistry and Biochemistry, University of Texas at Arlington, 700 Planetarium Pl., Arlington, TX 76019, USALife and Health Sciences Department, University of North Texas at Dallas, 7400 University Hills Blvd, Dallas, TX 75241, USAThe structures of two azide containing imidazole derivatives are reported. Allylic azides are fairly reactive making them attractive starting compounds to convert into amides. The first, C8H12N6O2S, contains one azide group with an Nα—Nβ distance of 1.229 (2) Å and an Nβ—Nγ distance of 1.128 (2) Å. The second, C8H11N9O2S, contains two azide groups with an average Nα—Nβ distance of 1.249 (2) Å and an average Nβ—Nγ distance of 1.132 (2) Å. Each compound contains a bulky protecting group (dimethylaminosulfonyl) which can be easily removed under mildly acidic conditions.http://scripts.iucr.org/cgi-bin/paper?S205698901900519Xcrystal structureimidazolenagelamideazideamide
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Lorenzo M. Cruz Raakiyah Y. Moore Marcela Torres Gutierrez Apsara K. Herath Carl J. Lovely Muhammed Yousufuddin
spellingShingle	Lorenzo M. Cruz Raakiyah Y. Moore Marcela Torres Gutierrez Apsara K. Herath Carl J. Lovely Muhammed Yousufuddin Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide Acta Crystallographica Section E: Crystallographic Communications crystal structure imidazole nagelamide azide amide
author_facet	Lorenzo M. Cruz Raakiyah Y. Moore Marcela Torres Gutierrez Apsara K. Herath Carl J. Lovely Muhammed Yousufuddin
author_sort	Lorenzo M. Cruz
title	Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide
title_short	Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide
title_full	Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide
title_fullStr	Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide
title_full_unstemmed	Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide
title_sort	crystal structures of 4-{(e)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-n,n-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(e)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-n,n-dimethylimidazole-1-sulfonamide
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2019-05-01
description	The structures of two azide containing imidazole derivatives are reported. Allylic azides are fairly reactive making them attractive starting compounds to convert into amides. The first, C8H12N6O2S, contains one azide group with an Nα—Nβ distance of 1.229 (2) Å and an Nβ—Nγ distance of 1.128 (2) Å. The second, C8H11N9O2S, contains two azide groups with an average Nα—Nβ distance of 1.249 (2) Å and an average Nβ—Nγ distance of 1.132 (2) Å. Each compound contains a bulky protecting group (dimethylaminosulfonyl) which can be easily removed under mildly acidic conditions.
topic	crystal structure imidazole nagelamide azide amide
url	http://scripts.iucr.org/cgi-bin/paper?S205698901900519X
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Crystal structures of 4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide and 2-[(imino-λ5-azanylidene)amino]-4-{(E)-3-[(imino-λ5-azanylidene)amino]prop-1-enyl}-N,N-dimethylimidazole-1-sulfonamide

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