Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands

Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands

In the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenylphosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt2Br2(C12H10P)H(C18H15P)2]·C4H10O or [Pt2(μ-H)(μ-PPh2)Br2(PPh3)2]·(C2H5)2O, the PtII atoms are coordinated in a distorted square-planar arrangement, with one hydrido and...

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Main Authors: Sakina Ouis, Djamil Azzedine Rouag, Lamia Bendjeddou, Corinne Bailly
Format: Article
Language:English
Published: International Union of Crystallography 2018-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
platinum(II) complex
hydrido bridge
phosphide ligand
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901800868X
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spelling doaj-ae6a77ce50694f218e55481c4f5c20162020-11-24T21:25:57ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-07-0174797798010.1107/S205698901800868Xxu5929Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligandsSakina Ouis0Djamil Azzedine Rouag1Lamia Bendjeddou2Corinne Bailly3Unité de Recherche Chimie de l'Environnement et Moléculaire, Structurale 'CHEMS', Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Frères Mentouri Constantine 1, 25000 Constantine, AlgeriaUnité de Recherche Chimie de l'Environnement et Moléculaire, Structurale 'CHEMS', Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Frères Mentouri Constantine 1, 25000 Constantine, AlgeriaUnité de Recherche Chimie de l'Environnement et Moléculaire, Structurale 'CHEMS', Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Frères Mentouri Constantine 1, 25000 Constantine, AlgeriaService de Radiocristallographie, Institut de Chimie, UMR 7177 CNRS-Université de Strasbourg, 1 Rue Blaise Pascal, 67008 Strasbourg cedex, FranceIn the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenylphosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt2Br2(C12H10P)H(C18H15P)2]·C4H10O or [Pt2(μ-H)(μ-PPh2)Br2(PPh3)2]·(C2H5)2O, the PtII atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C—H...·O and C—H...π interactions are present. This complex has a total number of 32 electrons, 16 electrons for each PtII atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio.http://scripts.iucr.org/cgi-bin/paper?S205698901800868Xplatinum(II) complexhydrido bridgephosphide ligandcrystal structure
collection DOAJ
language English
format Article
sources DOAJ
author Sakina Ouis
Djamil Azzedine Rouag
Lamia Bendjeddou
Corinne Bailly
spellingShingle Sakina Ouis
Djamil Azzedine Rouag
Lamia Bendjeddou
Corinne Bailly
Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
Acta Crystallographica Section E: Crystallographic Communications
platinum(II) complex
hydrido bridge
phosphide ligand
crystal structure
author_facet Sakina Ouis
Djamil Azzedine Rouag
Lamia Bendjeddou
Corinne Bailly
author_sort Sakina Ouis
title Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
title_short Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
title_full Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
title_fullStr Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
title_full_unstemmed Crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
title_sort crystal structure of homodinuclear platinum complex containing a metal–metal bond bridged by hydride and phosphide ligands
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2018-07-01
description In the title compound, μ-diphenylphosphido-μ-hydrido-bis[bromido(triphenylphosphane-κP)platinum(II)] diethyl ether monosolvate, [Pt2Br2(C12H10P)H(C18H15P)2]·C4H10O or [Pt2(μ-H)(μ-PPh2)Br2(PPh3)2]·(C2H5)2O, the PtII atoms are coordinated in a distorted square-planar arrangement, with one hydrido and one phosphido ligand bridging in a trans position. In the lattice, C—H...·O and C—H...π interactions are present. This complex has a total number of 32 electrons, 16 electrons for each PtII atom. One of the Br atoms is disordered over two positions in a 0.92:0.08 ratio.
topic platinum(II) complex
hydrido bridge
phosphide ligand
crystal structure
url http://scripts.iucr.org/cgi-bin/paper?S205698901800868X
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AT lamiabendjeddou crystalstructureofhomodinuclearplatinumcomplexcontainingametalmetalbondbridgedbyhydrideandphosphideligands
AT corinnebailly crystalstructureofhomodinuclearplatinumcomplexcontainingametalmetalbondbridgedbyhydrideandphosphideligands
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