Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]

Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]

The water-coordinated Ni2+ cation in the title compound, [Ni(C10H5N3O4)(H2O)]n, assumes an octahedral NiN3O3 coordination mode and is N,O-chelated by two deprotonated 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid (HPyImDC2−) ligands, forming a layer structure extending in the bc...

Full description

Bibliographic Details
Main Authors: Xue-Min Jing, Shu-zhe Gong, Li-Wei Xiao
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812001900
id doaj-ae52b7b720364a12817cbaa01d01ffc3
record_format Article
spelling doaj-ae52b7b720364a12817cbaa01d01ffc32020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m187m18710.1107/S1600536812001900Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]Xue-Min JingShu-zhe GongLi-Wei XiaoThe water-coordinated Ni2+ cation in the title compound, [Ni(C10H5N3O4)(H2O)]n, assumes an octahedral NiN3O3 coordination mode and is N,O-chelated by two deprotonated 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid (HPyImDC2−) ligands, forming a layer structure extending in the bc plane. The chains are arranged along the b-axis direction, forming a layer structure extending in the bc plane. O—H...O hydrogen bonding between the layers results in the formation of a three-dimensional supramolecular framework. The structure is isotypic with the Zn analogue [Li et al. (2009). Cryst. Growth Des. 6, 3423–3431].http://scripts.iucr.org/cgi-bin/paper?S1600536812001900
collection DOAJ
language English
format Article
sources DOAJ
author Xue-Min Jing
Shu-zhe Gong
Li-Wei Xiao
spellingShingle Xue-Min Jing
Shu-zhe Gong
Li-Wei Xiao
Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]
Acta Crystallographica Section E
author_facet Xue-Min Jing
Shu-zhe Gong
Li-Wei Xiao
author_sort Xue-Min Jing
title Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]
title_short Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]
title_full Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]
title_fullStr Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]
title_full_unstemmed Poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1H-imidazole-5-carboxylato-κ5N1,O5:N3,O4:N2]nickel(II)]
title_sort poly[aqua[μ3-4-carboxy-2-(pyridin-4-yl)-1h-imidazole-5-carboxylato-κ5n1,o5:n3,o4:n2]nickel(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-02-01
description The water-coordinated Ni2+ cation in the title compound, [Ni(C10H5N3O4)(H2O)]n, assumes an octahedral NiN3O3 coordination mode and is N,O-chelated by two deprotonated 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylic acid (HPyImDC2−) ligands, forming a layer structure extending in the bc plane. The chains are arranged along the b-axis direction, forming a layer structure extending in the bc plane. O—H...O hydrogen bonding between the layers results in the formation of a three-dimensional supramolecular framework. The structure is isotypic with the Zn analogue [Li et al. (2009). Cryst. Growth Des. 6, 3423–3431].
url http://scripts.iucr.org/cgi-bin/paper?S1600536812001900
work_keys_str_mv AT xueminjing polyaquaamp95634carboxy2pyridin4yl1himidazole5carboxylatoamp9545n1o5n3o4n2nickelii
AT shuzhegong polyaquaamp95634carboxy2pyridin4yl1himidazole5carboxylatoamp9545n1o5n3o4n2nickelii
AT liweixiao polyaquaamp95634carboxy2pyridin4yl1himidazole5carboxylatoamp9545n1o5n3o4n2nickelii
_version_ 1725065711286484992

Similar Items