Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)

Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)

In the title complex, [Cu(C12H6N2O5)(H2O)], the CuII ion is in a slightly distorted square-pyramidal coordination environment with two N and two O atoms from a 6,6′-oxydipicolinate ligand occupying the basal plane and a water ligand in the apical site. The dihedral angle between the tw...

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Main Authors: Jingya Sun, Xiangdi Tong
Format: Article
Language:English
Published: International Union of Crystallography 2010-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680905346X
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spelling doaj-ae32f20c13824684b2ea6c25da1605fd2020-11-25T01:13:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m70m7010.1107/S160053680905346XAqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)Jingya SunXiangdi TongIn the title complex, [Cu(C12H6N2O5)(H2O)], the CuII ion is in a slightly distorted square-pyramidal coordination environment with two N and two O atoms from a 6,6′-oxydipicolinate ligand occupying the basal plane and a water ligand in the apical site. The dihedral angle between the two pyridine rings is 5.51 (6)°. In the crystal structure, intermolecular O—H...O hydrogen bonds link molecules into a two-dimensional network. In addition, weak intermolecular C—H...O and C=O(lone pair)...π(ring) interactions, with O...ring-centroid distances of 3.697 (4) and 3.094 (4) Å, provide additional stabilization. http://scripts.iucr.org/cgi-bin/paper?S160053680905346X
collection DOAJ
language English
format Article
sources DOAJ
author Jingya Sun
Xiangdi Tong
spellingShingle Jingya Sun
Xiangdi Tong
Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)
Acta Crystallographica Section E
author_facet Jingya Sun
Xiangdi Tong
author_sort Jingya Sun
title Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)
title_short Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)
title_full Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)
title_fullStr Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)
title_full_unstemmed Aqua(6,6′-oxydipicolinato-κ2O,N,N′,O′)copper(II)
title_sort aqua(6,6′-oxydipicolinato-κ2o,n,n′,o′)copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-01-01
description In the title complex, [Cu(C12H6N2O5)(H2O)], the CuII ion is in a slightly distorted square-pyramidal coordination environment with two N and two O atoms from a 6,6′-oxydipicolinate ligand occupying the basal plane and a water ligand in the apical site. The dihedral angle between the two pyridine rings is 5.51 (6)°. In the crystal structure, intermolecular O—H...O hydrogen bonds link molecules into a two-dimensional network. In addition, weak intermolecular C—H...O and C=O(lone pair)...π(ring) interactions, with O...ring-centroid distances of 3.697 (4) and 3.094 (4) Å, provide additional stabilization.
url http://scripts.iucr.org/cgi-bin/paper?S160053680905346X
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AT xiangditong aqua66amp8242oxydipicolinatoamp9542onnamp8242oamp8242copperii
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