A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units

A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units

A new homochiral multifunctional metal-organic framework, [Zn2(CTBA)2·H2O] (JUC-112), was synthesized under solvothermal conditions, through the design of chiral ligand 4-(3-carboxy-2,2,3-trimethylcyclopentanecarboxamido) benzoic acid (H2CTBA) based on camphoric acid as building block. The crystal s...

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Main Authors: Kun Cai, Nian Zhao, Ning Zhang, Fu-Xing Sun, Qing Zhao, Guang-Shan Zhu
Format: Article
Language:English
Published: MDPI AG 2017-04-01
Series:Nanomaterials
Subjects:
metal-organic frameworks (MOFs)
homochiral
camphoric acid
multifunction
Online Access:http://www.mdpi.com/2079-4991/7/4/88
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spelling doaj-ae0f300cd42c49c7adbe9afe331b5e532020-11-24T22:50:29ZengMDPI AGNanomaterials2079-49912017-04-01748810.3390/nano7040088nano7040088A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building UnitsKun Cai0Nian Zhao1Ning Zhang2Fu-Xing Sun3Qing Zhao4Guang-Shan Zhu5State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, ChinaState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, ChinaState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, ChinaState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, ChinaChina-Japan Union Hospital, Jilin University, Changchun 130033, ChinaKey Laboratory of Polyoxometalate Science of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, ChinaA new homochiral multifunctional metal-organic framework, [Zn2(CTBA)2·H2O] (JUC-112), was synthesized under solvothermal conditions, through the design of chiral ligand 4-(3-carboxy-2,2,3-trimethylcyclopentanecarboxamido) benzoic acid (H2CTBA) based on camphoric acid as building block. The crystal structure of the new material is a 2-dimensional (2D) chiral layer packed with infinite rod-shaped secondary building units (SBUs). The homochiral framework was identified by circular dichroism (CD) spectrum. Thermogravimetric measurement indicates its high thermal stability up to 450 °C. In addition, JUC-112 exhibits the capability of separating water from alcohols, second-order nonlinear optical effect, and photoluminescence.http://www.mdpi.com/2079-4991/7/4/88metal-organic frameworks (MOFs)homochiralcamphoric acidmultifunction
collection DOAJ
language English
format Article
sources DOAJ
author Kun Cai
Nian Zhao
Ning Zhang
Fu-Xing Sun
Qing Zhao
Guang-Shan Zhu
spellingShingle Kun Cai
Nian Zhao
Ning Zhang
Fu-Xing Sun
Qing Zhao
Guang-Shan Zhu
A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units
Nanomaterials
metal-organic frameworks (MOFs)
homochiral
camphoric acid
multifunction
author_facet Kun Cai
Nian Zhao
Ning Zhang
Fu-Xing Sun
Qing Zhao
Guang-Shan Zhu
author_sort Kun Cai
title A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units
title_short A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units
title_full A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units
title_fullStr A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units
title_full_unstemmed A Homochiral Multifunctional Metal-Organic Framework with Rod-Shaped Secondary Building Units
title_sort homochiral multifunctional metal-organic framework with rod-shaped secondary building units
publisher MDPI AG
series Nanomaterials
issn 2079-4991
publishDate 2017-04-01
description A new homochiral multifunctional metal-organic framework, [Zn2(CTBA)2·H2O] (JUC-112), was synthesized under solvothermal conditions, through the design of chiral ligand 4-(3-carboxy-2,2,3-trimethylcyclopentanecarboxamido) benzoic acid (H2CTBA) based on camphoric acid as building block. The crystal structure of the new material is a 2-dimensional (2D) chiral layer packed with infinite rod-shaped secondary building units (SBUs). The homochiral framework was identified by circular dichroism (CD) spectrum. Thermogravimetric measurement indicates its high thermal stability up to 450 °C. In addition, JUC-112 exhibits the capability of separating water from alcohols, second-order nonlinear optical effect, and photoluminescence.
topic metal-organic frameworks (MOFs)
homochiral
camphoric acid
multifunction
url http://www.mdpi.com/2079-4991/7/4/88
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