Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate

Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate

The title compound, [Zn2V2(C5H6NO7P)2O2(H2O)10]·2H2O, contains a [V2O2(pmida)2]4− dimeric anionic unit [where H4pmida is N-(phosphonomethyl)iminodiacetic acid] lying on a centre of symmetry which is exo-coordinated via the two deprotonated phosphonate groups to two Zn2+ cations, w...

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Main Authors: Fa-Nian Shi, Jacek Klinowski, Tito Trindade, João Rocha, Filipe A. Almeida Paz, Luís Cunha-Silva
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536807062253
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spelling doaj-adf317c94bbf457381720d98dd1b289d2020-11-25T02:14:00ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m39m4010.1107/S1600536807062253Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrateFa-Nian ShiJacek KlinowskiTito TrindadeJoão RochaFilipe A. Almeida PazLuís Cunha-SilvaThe title compound, [Zn2V2(C5H6NO7P)2O2(H2O)10]·2H2O, contains a [V2O2(pmida)2]4− dimeric anionic unit [where H4pmida is N-(phosphonomethyl)iminodiacetic acid] lying on a centre of symmetry which is exo-coordinated via the two deprotonated phosphonate groups to two Zn2+ cations, with the coordination environment of Zn completed by five water molecules. The crystal packing is mediated by an extensive network of strong and highly directional O—H...O hydrogen bonds involving the water molecules (coordinated and uncoordinated) and the functional groups of pmida4−, leading to a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536807062253
collection DOAJ
language English
format Article
sources DOAJ
author Fa-Nian Shi
Jacek Klinowski
Tito Trindade
João Rocha
Filipe A. Almeida Paz
Luís Cunha-Silva
spellingShingle Fa-Nian Shi
Jacek Klinowski
Tito Trindade
João Rocha
Filipe A. Almeida Paz
Luís Cunha-Silva
Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate
Acta Crystallographica Section E
author_facet Fa-Nian Shi
Jacek Klinowski
Tito Trindade
João Rocha
Filipe A. Almeida Paz
Luís Cunha-Silva
author_sort Fa-Nian Shi
title Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate
title_short Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate
title_full Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate
title_fullStr Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate
title_full_unstemmed Decaaquadioxidobis[μ3-N-(phosphonatomethyl)iminodiacetato]dizinc(II)divanadium(IV) dihydrate
title_sort decaaquadioxidobis[μ3-n-(phosphonatomethyl)iminodiacetato]dizinc(ii)divanadium(iv) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The title compound, [Zn2V2(C5H6NO7P)2O2(H2O)10]·2H2O, contains a [V2O2(pmida)2]4− dimeric anionic unit [where H4pmida is N-(phosphonomethyl)iminodiacetic acid] lying on a centre of symmetry which is exo-coordinated via the two deprotonated phosphonate groups to two Zn2+ cations, with the coordination environment of Zn completed by five water molecules. The crystal packing is mediated by an extensive network of strong and highly directional O—H...O hydrogen bonds involving the water molecules (coordinated and uncoordinated) and the functional groups of pmida4−, leading to a three-dimensional supramolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536807062253
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