Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate]
In the crystal structure of the title compound, {[Cu(C8H6O9)(C12H8N2)]·0.69H2O}n, the CuII atom has a distorted octahedral geometry, coordinated by four O atoms from two 3,4-dicarboxytetrahydrofuran-2,5-dicarboxylate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the ca...
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| Language: | English |
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International Union of Crystallography
2008-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808027918 |
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doaj-adf25087fcf140c2bf2c044e8b11e0dc2020-11-25T02:46:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1245m124510.1107/S1600536808027918Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate]Yuanqi LüIn the crystal structure of the title compound, {[Cu(C8H6O9)(C12H8N2)]·0.69H2O}n, the CuII atom has a distorted octahedral geometry, coordinated by four O atoms from two 3,4-dicarboxytetrahydrofuran-2,5-dicarboxylate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the carboxylate groups bridges the CuII atoms, forming a zigzag chain running along the b axis. The chains are linked by a π–π interaction between aromatic rings with a centroid-to-centroid distance of 3.567 (1) Å, and by hydrogen bonds between the carboxylate group and the disordered water molecule, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808027918 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Yuanqi Lü |
| spellingShingle |
Yuanqi Lü Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate] Acta Crystallographica Section E |
| author_facet |
Yuanqi Lü |
| author_sort |
Yuanqi Lü |
| title |
Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate] |
| title_short |
Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate] |
| title_full |
Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate] |
| title_fullStr |
Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate] |
| title_full_unstemmed |
Poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4O1,O2,O5:O2′)(1,10-phenanthroline-κ2N,N′)copper(II)] 0.69-hydrate] |
| title_sort |
poly[[(μ-3,4-dicarboxytetrahydrofuran-2,5-dicarboxylato-κ4o1,o2,o5:o2′)(1,10-phenanthroline-κ2n,n′)copper(ii)] 0.69-hydrate] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2008-10-01 |
| description |
In the crystal structure of the title compound, {[Cu(C8H6O9)(C12H8N2)]·0.69H2O}n, the CuII atom has a distorted octahedral geometry, coordinated by four O atoms from two 3,4-dicarboxytetrahydrofuran-2,5-dicarboxylate ligands and two N atoms from one 1,10-phenanthroline ligand. One of the carboxylate groups bridges the CuII atoms, forming a zigzag chain running along the b axis. The chains are linked by a π–π interaction between aromatic rings with a centroid-to-centroid distance of 3.567 (1) Å, and by hydrogen bonds between the carboxylate group and the disordered water molecule, forming a three-dimensional network. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536808027918 |
| work_keys_str_mv |
AT yuanqil252 poly95634dicarboxytetrahydrofuran25dicarboxylato9544o1o2o5o28242110phenanthroline9542nn8242copperii069hydrate |
| _version_ |
1724756246903390208 |