The Production of Vinyl Acetate Monomer as a Co-Product from the Non-Catalytic Cracking of Soybean Oil

Valuable chemical by-products can increase the economic viability of renewable transportation fuel facilities while increasing the sustainability of the chemical and associated industries. A study was performed to demonstrate that commercial quality chemical products could be produced using the non-...

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Bibliographic Details
Main Authors: Benjamin Jones, Michael Linnen, Brian Tande, Wayne Seames
Format: Article
Language:English
Published: MDPI AG 2015-08-01
Series:Processes
Subjects:
Online Access:http://www.mdpi.com/2227-9717/3/3/619
Description
Summary:Valuable chemical by-products can increase the economic viability of renewable transportation fuel facilities while increasing the sustainability of the chemical and associated industries. A study was performed to demonstrate that commercial quality chemical products could be produced using the non-catalytic cracking of crop oils. Using this decomposition technique generates a significant concentration of C2−C10 fatty acids which can be isolated and purified as saleable co-products along with transportation fuels. A process scheme was developed and replicated in the laboratory to demonstrate this capability. Using this scheme, an acetic acid by-product was isolated and purified then reacted with ethylene derived from renewable ethanol to generate a sample of vinyl acetate monomer. This sample was assessed by a major chemical company and found to be of acceptable quality for commercial production of polyvinyl acetate and other products.
ISSN:2227-9717