Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)

Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)

In the molecular structure of the title compound, [NiCl2(C7H12N2S)2], the NiII atom has a distorted tetrahedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the NiII cation, which lies on a twofold rotation axis, are Cl—Ni—Cl...

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Main Authors: Aziza Ahmida, Ulrich Flörke, Hans Egold, Gerald Henkel
Format: Article
Language:English
Published: International Union of Crystallography 2015-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
nickel(II) complex
1,3,4,5-tetramethylimidazole-2-thione ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015012281
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spelling doaj-ad77b7537f2d497b9d4ee9ac55c139232020-11-24T22:33:50ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-08-01718m147m14710.1107/S2056989015012281hp2071Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)Aziza Ahmida0Ulrich Flörke1Hans Egold2Gerald Henkel3Department Chemie, Fakultät für Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, GermanyDepartment Chemie, Fakultät für Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, GermanyDepartment Chemie, Fakultät für Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, GermanyDepartment Chemie, Fakultät für Naturwissenschaften, Universität Paderborn, Warburgerstrasse 100, D-33098 Paderborn, GermanyIn the molecular structure of the title compound, [NiCl2(C7H12N2S)2], the NiII atom has a distorted tetrahedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the NiII cation, which lies on a twofold rotation axis, are Cl—Ni—Cl = 115.58 (3)° and S—Ni—S = 94.55 (3)°. All other angles at the central NiII atom range from 109.46 (2) to 112.96 (2)°. The C—S—Ni angle is 99.91 (6)°. The planes of two imidazolium rings make a dihedral angle of 70.56 (6)°.http://scripts.iucr.org/cgi-bin/paper?S2056989015012281crystal structurenickel(II) complex1,3,4,5-tetramethylimidazole-2-thione ligand
collection DOAJ
language English
format Article
sources DOAJ
author Aziza Ahmida
Ulrich Flörke
Hans Egold
Gerald Henkel
spellingShingle Aziza Ahmida
Ulrich Flörke
Hans Egold
Gerald Henkel
Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
nickel(II) complex
1,3,4,5-tetramethylimidazole-2-thione ligand
author_facet Aziza Ahmida
Ulrich Flörke
Hans Egold
Gerald Henkel
author_sort Aziza Ahmida
title Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)
title_short Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)
title_full Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)
title_fullStr Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)
title_full_unstemmed Crystal structure of dichloridobis(1,3,4,5-tetramethyl-1H-imidazol-2-ium-2-thiolate-κS)nickel(II)
title_sort crystal structure of dichloridobis(1,3,4,5-tetramethyl-1h-imidazol-2-ium-2-thiolate-κs)nickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-08-01
description In the molecular structure of the title compound, [NiCl2(C7H12N2S)2], the NiII atom has a distorted tetrahedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the NiII cation, which lies on a twofold rotation axis, are Cl—Ni—Cl = 115.58 (3)° and S—Ni—S = 94.55 (3)°. All other angles at the central NiII atom range from 109.46 (2) to 112.96 (2)°. The C—S—Ni angle is 99.91 (6)°. The planes of two imidazolium rings make a dihedral angle of 70.56 (6)°.
topic crystal structure
nickel(II) complex
1,3,4,5-tetramethylimidazole-2-thione ligand
url http://scripts.iucr.org/cgi-bin/paper?S2056989015012281
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AT ulrichflorke crystalstructureofdichloridobis1345tetramethyl1himidazol2ium2thiolateksnickelii
AT hansegold crystalstructureofdichloridobis1345tetramethyl1himidazol2ium2thiolateksnickelii
AT geraldhenkel crystalstructureofdichloridobis1345tetramethyl1himidazol2ium2thiolateksnickelii
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