fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate

fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate

In the structure of the title compound, [Fe(C7H7N2O2)3]·CH3CH2OH, the FeIII atom is in a distorted octahedral O6 environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl...

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Main Authors: Ahmed B. M. Alagha, Declan Gaynor, Helge Müller-Bunz, Kevin B. Nolan, Laavanya Parthasarathi
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681002413X
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spelling doaj-acf623e26145496aab59c0d5c970b0572020-11-25T01:27:09ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667m853m85410.1107/S160053681002413Xfac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvateAhmed B. M. AlaghaDeclan GaynorHelge Müller-BunzKevin B. NolanLaavanya ParthasarathiIn the structure of the title compound, [Fe(C7H7N2O2)3]·CH3CH2OH, the FeIII atom is in a distorted octahedral O6 environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent molecule is disordered over two positions with occupancies of 0.626 (13) and 0.374 (13), respectively. The cocrystallized ethanol molecule is hydrogen bonded to one of the hydroxamate O atoms. O—H...O and N—H...O interactions generate infinite three-dimensional networks along [100], [010] and [001]. http://scripts.iucr.org/cgi-bin/paper?S160053681002413X
collection DOAJ
language English
format Article
sources DOAJ
author Ahmed B. M. Alagha
Declan Gaynor
Helge Müller-Bunz
Kevin B. Nolan
Laavanya Parthasarathi
spellingShingle Ahmed B. M. Alagha
Declan Gaynor
Helge Müller-Bunz
Kevin B. Nolan
Laavanya Parthasarathi
fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate
Acta Crystallographica Section E
author_facet Ahmed B. M. Alagha
Declan Gaynor
Helge Müller-Bunz
Kevin B. Nolan
Laavanya Parthasarathi
author_sort Ahmed B. M. Alagha
title fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate
title_short fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate
title_full fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate
title_fullStr fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate
title_full_unstemmed fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate
title_sort fac-tris(4-aminobenzohydroxamato)iron(iii) ethanol solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description In the structure of the title compound, [Fe(C7H7N2O2)3]·CH3CH2OH, the FeIII atom is in a distorted octahedral O6 environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent molecule is disordered over two positions with occupancies of 0.626 (13) and 0.374 (13), respectively. The cocrystallized ethanol molecule is hydrogen bonded to one of the hydroxamate O atoms. O—H...O and N—H...O interactions generate infinite three-dimensional networks along [100], [010] and [001].
url http://scripts.iucr.org/cgi-bin/paper?S160053681002413X
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AT declangaynor factris4aminobenzohydroxamatoironiiiethanolsolvate
AT helgemamp252llerbunz factris4aminobenzohydroxamatoironiiiethanolsolvate
AT kevinbnolan factris4aminobenzohydroxamatoironiiiethanolsolvate
AT laavanyaparthasarathi factris4aminobenzohydroxamatoironiiiethanolsolvate
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