fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate

fac-Tris(4-aminobenzohydroxamato)iron(III) ethanol solvate

In the structure of the title compound, [Fe(C7H7N2O2)3]·CH3CH2OH, the FeIII atom is in a distorted octahedral O6 environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl...

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Bibliographic Details
Main Authors: Ahmed B. M. Alagha, Declan Gaynor, Helge Müller-Bunz, Kevin B. Nolan, Laavanya Parthasarathi
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681002413X
Description
Summary:In the structure of the title compound, [Fe(C7H7N2O2)3]·CH3CH2OH, the FeIII atom is in a distorted octahedral O6 environment with the three hydroxamate O atoms (and the three carbonyl O atoms) arranged in a fac configuration and one of the hydroxamate ligands being puckered. The methyl C atom of the ethanol solvent molecule is disordered over two positions with occupancies of 0.626 (13) and 0.374 (13), respectively. The cocrystallized ethanol molecule is hydrogen bonded to one of the hydroxamate O atoms. O—H...O and N—H...O interactions generate infinite three-dimensional networks along [100], [010] and [001].
ISSN:1600-5368

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