Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]

The reaction of Ag2O with l-valine (l-Hval, C5H11NO2) in a 1:2 molar ratio in water, followed by vapour diffusion, afforded a coordination polymer of the title compound, [Ag(C5H10NO2)]n, with N—Ag—O repeat units, which is classified as a type III silver(I) complex with amino acid ligands. The asymme...

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Main Authors:	Yoshitaka Takagi, Youhei Okamoto, Chisato Inoue, Noriko Chikaraishi Kasuga, Kenji Nomiya
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-03-01
Series:	Acta Crystallographica Section E: Crystallographic Communications
Subjects:	silver(I) complex with amino acid Ag...Ag interaction coordination polymer hydrogen bonding crystal structure
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S2056989017001815

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record_format	Article
spelling	doaj-acd9f68c4a6848219c26b6e597d87f7e2020-11-24T22:41:23ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-03-0173335435710.1107/S2056989017001815is5463Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]Yoshitaka Takagi0Youhei Okamoto1Chisato Inoue2Noriko Chikaraishi Kasuga3Kenji Nomiya4Department of Chemistry, Faculty of Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, JapanDepartment of Chemistry, Faculty of Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, JapanDepartment of Chemistry, Faculty of Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, JapanDepartment of Chemistry, Faculty of Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, JapanDepartment of Chemistry, Faculty of Science, Kanagawa University, Tsuchiya, Hiratsuka, Kanagawa 259-1293, JapanThe reaction of Ag2O with l-valine (l-Hval, C5H11NO2) in a 1:2 molar ratio in water, followed by vapour diffusion, afforded a coordination polymer of the title compound, [Ag(C5H10NO2)]n, with N—Ag—O repeat units, which is classified as a type III silver(I) complex with amino acid ligands. The asymmetric unit consists of two independent units of [Ag(l-val)]. In the crystal, the polymeric chains run along [101], and neighbouring chains are linked via a weak Ag...Ag interaction and N—H...O hydrogen bonds. The title complex exhibited antimicrobial activity against selected bacteria (Escherichia coli, Bacillus subtilis, Staphylococcous aureus and Psedomonas aeruginosa).http://scripts.iucr.org/cgi-bin/paper?S2056989017001815silver(I) complex with amino acidAg...Ag interactioncoordination polymerhydrogen bondingcrystal structure
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Yoshitaka Takagi Youhei Okamoto Chisato Inoue Noriko Chikaraishi Kasuga Kenji Nomiya
spellingShingle	Yoshitaka Takagi Youhei Okamoto Chisato Inoue Noriko Chikaraishi Kasuga Kenji Nomiya Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O] Acta Crystallographica Section E: Crystallographic Communications silver(I) complex with amino acid Ag...Ag interaction coordination polymer hydrogen bonding crystal structure
author_facet	Yoshitaka Takagi Youhei Okamoto Chisato Inoue Noriko Chikaraishi Kasuga Kenji Nomiya
author_sort	Yoshitaka Takagi
title	Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]
title_short	Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]
title_full	Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]
title_fullStr	Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]
title_full_unstemmed	Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]
title_sort	crystal structure of catena-poly[silver(i)-μ-l-valinato-κ2n:o]
publisher	International Union of Crystallography
series	Acta Crystallographica Section E: Crystallographic Communications
issn	2056-9890
publishDate	2017-03-01
description	The reaction of Ag2O with l-valine (l-Hval, C5H11NO2) in a 1:2 molar ratio in water, followed by vapour diffusion, afforded a coordination polymer of the title compound, [Ag(C5H10NO2)]n, with N—Ag—O repeat units, which is classified as a type III silver(I) complex with amino acid ligands. The asymmetric unit consists of two independent units of [Ag(l-val)]. In the crystal, the polymeric chains run along [101], and neighbouring chains are linked via a weak Ag...Ag interaction and N—H...O hydrogen bonds. The title complex exhibited antimicrobial activity against selected bacteria (Escherichia coli, Bacillus subtilis, Staphylococcous aureus and Psedomonas aeruginosa).
topic	silver(I) complex with amino acid Ag...Ag interaction coordination polymer hydrogen bonding crystal structure
url	http://scripts.iucr.org/cgi-bin/paper?S2056989017001815
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Crystal structure of catena-poly[silver(I)-μ-l-valinato-κ2N:O]

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