6-[Bis(ethoxycarbonyl)methyl]-6-deoxy-1,2;3,4-di-O-isopropylidene-d-galactopyranose

6-[Bis(ethoxycarbonyl)methyl]-6-deoxy-1,2;3,4-di-O-isopropylidene-d-galactopyranose

The title compound, C19H30O9, was prepared by substitution at the C6 position in 1,2;3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-d-galactose using sodium ethoxymalonate in dimethylformamide. The conformation is skew-boat 0S2, slightly distorted towards boat B2,5. The inflexible pyranose str...

Full description

Bibliographic Details
Main Authors:	Victor N. Nemykin, Paulo R. da Silva, Bogdan Doboszewski, Alexander Y. Nazarenko
Format:	Article
Language:	English
Published:	International Union of Crystallography 2010-12-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536810046921

Similar Items

3-Deoxy-1,2-di-O-isopropylidene-5-O-tosyl-d-threo-pentofuranose
by: Bogdan Doboszewski, et al.
Published: (2012-04-01)

Polymers and copolymers of unsaturated derivatives of Di-O-isopropylidene-D-galactopyranose
by: Colquhoun, Joseph Adams
Published: (1969)

Methyl 6-deoxy-6-iodo-2,3-O-isopropylidene-α-d-mannopyranoside
by: Zeynep Gültekin, et al.
Published: (2013-09-01)

Crystal structure of 6,6-bis(methyl2,3-O-isopropylidene-6-deoxy-α-Dmannopyranoside), C20H34O10
by: Gültekin Z., et al.
Published: (2002-12-01)

6-Deoxy-3,4-O-isopropylidene-2-C-methyl-l-galactono-1,5-lactone
by: Sarah F. Jenkinson, et al.
Published: (2011-09-01)

Crystal structure of 6-azido-6-deoxy-1,2-O-isopropylidene-α-d-glucofuranose
by: Adam Wood, et al.
Published: (2020-10-01)

Crystal structure of 1-deoxy-1-(3-hydroxypropyl)-O-triphenylmethyl-β- D-lyxofuranose, C27H30O5
by: Doboszewski Bogdan, et al.
Published: (2011-03-01)

Crystal structure of 1,2,3,4-di-O-methylene-α-d-galactopyranose
by: Ioannis Tiritiris, et al.
Published: (2015-12-01)

Crystal structure of methyl 6-deoxy-6-iodo-2,3-O-isopropylidene-α-Dmannopyranoside, C10H17IO5
by: Hahn D. U., et al.
Published: (2002-12-01)

Crystal structure of methyl 6-deoxy-6-iodo-2,3-O-isopropylidene-α-Dmannopyranoside, C10H17IO5
by: Hahn D. U., et al.
Published: (2002-12-01)

An orthorhombic polymorph of 6-deoxy-6-iodo-1,2:3,4-di-O-isopropylidene-&#945;-d-galactopyranoside
by: Hoong-Kun Fun, et al.
Published: (2009-08-01)

Synthesis, Crystal Structure, and Conformation of Methyl 5-Oacetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-ÃŽÂ²-L-gulofuranoside
by: Dalma GyepesovÃƒÂ¡, et al.
Published: (2002-05-01)

Crystal structure of 3-deoxy-3-nitromethyl-1,2;5,6-di-O-isopropylidene-α-d-allofuranose
by: Jevgeņija Lugiņina, et al.
Published: (2016-03-01)

2-Deoxy-2,3-O-isopropylidene-2,4-di-C-methyl-&#946;-l-arabinose
Published: (2009-03-01)

3&#8242;-O-Acetyl-2&#8242;-deoxyuridine
by: Victor N. Nemykin, et al.
Published: (2011-01-01)

Partly methylated derivatives of 6-deoxy-hexoses
by: Charalambous, George
Published: (1953)

Ethyl {6-[6-(ethoxycarbonyl)picolinamidocarbonyl]picolinamidocarbonyl}picolinate
by: Xiao Li, et al.
Published: (2009-01-01)

tert-Butyl 2-deoxy-4,5-O-isopropylidene-d-gluconate
by: David J. Watkin, et al.
Published: (2008-10-01)

Methyl 6-deoxy-6-iodo-&#945;-d-galactoside
by: Shivali A. Gulab, et al.
Published: (2010-07-01)

Methyl 6-azido-6-deoxy-&#945;-d-galactoside
by: Janice M. H. Cheng, et al.
Published: (2011-08-01)

Crystal structure of 4-amino-4-deoxy-5,6-O-isopropylidene-D-gulitol, C9H19NO5
by: Henkel S., et al.
Published: (1997-12-01)

Crystal structure of 4-amino-4-deoxy-5,6-O-isopropylidene-D-gulitol, C9H19NO5
by: Henkel S., et al.
Published: (1997-12-01)

7-Azido-N,N-diethyl-4,5-O-isopropylidene-4-C-methyl-3,6-anhydro-7-deoxy-d-glycero-d-manno-heptonamide
by: David J. Watkin, et al.
Published: (2009-02-01)

Crystal structure of 3-C-(N-benzyloxycarbonyl)aminomethyl-3-deoxy-1,2:5,6-di-O-isopropylidene-α-d-allofuranose
by: Vitalijs Rjabovs, et al.
Published: (2015-10-01)

6-Azido-3-O-benzyl-6-deoxy-N,N-diethyl-1,2-O-isopropylidene-d-glycero-&#945;-d-gluco-heptofuranuronamide
by: M. S. Pino-Gonz&#225;lez, et al.
Published: (2011-01-01)

4-[3,5-Bis(ethoxycarbonyl)-2,6-dimethyl-4-pyridyl]pyridinium nitrate
by: Yumei Li
Published: (2010-05-01)

1,2:5,6-Di-O-isopropylidene-3-C-methyl-α-d-allofuranose
by: Luana da Silva Magalhães Forezi, et al.
Published: (2013-10-01)

2-Azido-2-deoxy-3,4-O-isopropylidene-2-C-methyl-d-talono-1,5-lactone
by: Sarah F. Jenkinson, et al.
Published: (2010-05-01)

3,5-Bis(ethoxycarbonyl)-2,6-dimethyl-1,4-dihydropyridine-4-carboxylic acid
by: De-Hong Wu, et al.
Published: (2009-08-01)

Bis(1,2,3,4-tetrahydroquinolin-6-yl)methane
by: Hai-Jun Shen, et al.
Published: (2008-09-01)

QM/MM molecular dynamics study of the galactopyranose → galactofuranose reaction catalysed by Trypanosoma cruzi UDP-galactopyranose mutase.
by: Gustavo Pierdominici-Sottile, et al.
Published: (2014-01-01)

1-Dibenzylamino-1-deoxy-4,5-O-isopropylidene-&#946;-d-fructopyranose
by: Shiyong Huo, et al.
Published: (2011-02-01)

Synthesis of 6-deoxy-6-fluorosugars
by: Roig, Ricard
Published: (2006)

6-Deoxy-6-fluoro-d-galactose
by: Sarah F. Jenkinson, et al.
Published: (2010-06-01)

Structural and inhibition studies on UDP-galactopyranose mutase
by: Karunan Partha, Sarathy
Published: (2011)

4-Cyclopropyl-1-(6′-deoxy-1′,2′-O-isopropylidene-α-d-glucofuranosyl)-1H-1,2,3-triazole
by: Qiurong Zhang, et al.
Published: (2013-09-01)

2,6-Anhydro-1,3-di-O-benzyl-d-mannitol
by: Edmilson Clarindo de Siqueira, et al.
Published: (2011-07-01)

1,3-Bis(2-oxopropyl)thymine
by: Bogdan Doboszewski, et al.
Published: (2020-02-01)

Crystal structure of (S)-1-O-tert-butyldiphenylsilylglycerol: eight chiral molecules in a triclinic cell
by: Bogdan Doboszewski, et al.
Published: (2018-09-01)

3-Ethoxycarbonyl-2-hydroxy-6-methoxy-4-methylbenzoic acid
by: Yun-Xia Deng, et al.
Published: (2012-05-01)