Visible-Light, Iodine-Promoted Formation of N-Sulfonyl Imines and N-Alkylsulfonamides from Aldehydes and Hypervalent Iodine Reagents

Visible-Light, Iodine-Promoted Formation of N-Sulfonyl Imines and N-Alkylsulfonamides from Aldehydes and Hypervalent Iodine Reagents

Alternative synthetic methodology for the direct installation of sulfonamide functionality is a highly desirable goal within the domain of drug discovery and development. The formation of synthetically valuable N-sulfonyl imines from a range of aldehydes, sulfonamides, and PhI(OAc)2 under practical...

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Bibliographic Details
Main Authors: Megan D. Hopkins, Zachary C. Brandeburg, Andrew J. Hanson, Angus A. Lamar
Format: Article
Language:English
Published: MDPI AG 2018-07-01
Series:Molecules
Subjects:
visible-light
iodine promoted
N-sulfonyl imine
iodobenzene diacetate (PIDA)
sulfonamide
hypervalent iodine
aldimine synthesis
iminoiodinane
nitrogen-centered radical
Online Access:http://www.mdpi.com/1420-3049/23/8/1838

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