Synthesis and Characterization of Some New Thermal Stable Polymers - Polymerization of N-[4-N´ -(Benzylamino-carbonyl)phenyl]maleimide
This article describes the synthesis and characterization of homopolymer (H-BCPM) of N-[4-N'-(benzylamino-carbonyl) phenyl] maleimide (N-BACPMI) and copolymer (C-BCPM) of N-BACPMI with n-butyl acrylate (BA). The new monomer was synthesized from p-aminobenzoic acid, maleic anhydride and benzylam...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Hindawi Limited
2007-01-01
|
| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2007/857326 |
| Summary: | This article describes the synthesis and characterization of homopolymer (H-BCPM) of N-[4-N'-(benzylamino-carbonyl) phenyl] maleimide (N-BACPMI) and copolymer (C-BCPM) of N-BACPMI with n-butyl acrylate (BA). The new monomer was synthesized from p-aminobenzoic acid, maleic anhydride and benzylamine. The homopolymerization of N-BACPMI is initiated by free radical using AIBN in THF solvent at 65°C. Radical copolymerization of N-BACPMI with BA, initiated by AIBN, was performed in THF solvent using equimolar amount. Effect of the different free radical initiator AIBN, BPO and solvents p-Dioxane, THF, DMF and DMSO was studied. Homopolymer and Copolymer were characterized by intrinsic viscosity, solubility test, FT-IR, 1H-NMR spectral analysis and elemental analysis. Thermal behaviour was studied by Thermo gravimetric analysis. |
|---|---|
| ISSN: | 0973-4945 2090-9810 |