Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids

Reactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Comple...

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Main Authors: Satish C. Dixit, Rohit K. Singh
Format: Article
Language:English
Published: Hindawi Limited 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/631391
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spelling doaj-ab39797e0b364e50807bdbc2263898b12020-11-25T00:12:35ZengHindawi LimitedE-Journal of Chemistry0973-49452090-98102012-01-019274474810.1155/2012/631391Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic AcidsSatish C. Dixit0Rohit K. Singh1Deptt. of Chemistry, D.B.S. College, Kanpur-208006, IndiaDeptt. of Chemistry, Pt. J.L.N. College, Banda (U.P.), IndiaReactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Zr(QAH)Cl, Cp2Zr(QAH)2, Cp2Zr(PAH)Cl, Cp2Zr(PAH)2, Cp2Zr(IAH)Cl, Cp2Zr(IAH)2, Cp2Zr(CAH)Cl, Cp2Zr(CAH)2, Cp2Zr(DAH)Cl and Cp2Zr(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data.http://dx.doi.org/10.1155/2012/631391
collection DOAJ
language English
format Article
sources DOAJ
author Satish C. Dixit
Rohit K. Singh
spellingShingle Satish C. Dixit
Rohit K. Singh
Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
E-Journal of Chemistry
author_facet Satish C. Dixit
Rohit K. Singh
author_sort Satish C. Dixit
title Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_short Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_full Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_fullStr Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_full_unstemmed Some New Derivatives of Organozirconium(IV) with Pyridinedicarboxylic Acids
title_sort some new derivatives of organozirconium(iv) with pyridinedicarboxylic acids
publisher Hindawi Limited
series E-Journal of Chemistry
issn 0973-4945
2090-9810
publishDate 2012-01-01
description Reactions of dichlorobis(cyclopentadienyl)zirconium(IV) with pyridinedicarboxylic acids viz. quinolinic acids (QAH2), 2,4-pyridine dicarboxylic acid (PAH2), isocinchomeronic acid (IAH2), cinchomeronic acid (CAH2) and dinicotinic acid (DAH2) were carried out in different stoichiometric ratios. Complexes of the type Cp2Zr(QAH)Cl, Cp2Zr(QAH)2, Cp2Zr(PAH)Cl, Cp2Zr(PAH)2, Cp2Zr(IAH)Cl, Cp2Zr(IAH)2, Cp2Zr(CAH)Cl, Cp2Zr(CAH)2, Cp2Zr(DAH)Cl and Cp2Zr(DAH)2 were obtained. These new complexes were characterized on the basis of their elemental analyses, electrical conductance, magnetic moment and spectral data.
url http://dx.doi.org/10.1155/2012/631391
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