Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)

Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)

The structure of the title compound, [Ph3P=N=PPh3]+[Ph3SnCl2]− or (C36H30NP2)[Sn(C6H5)3Cl2], obtained as a by product of the reaction between Ph3SnCl and [Ph3P=N=PPh3]+·HSeO3−, consists of discrete essentially isolated ions. Both the cation and the anion lie...

Full description

Bibliographic Details
Main Authors: Giovanni Predieri, Claudia Graiff, Lucio De Lorentiis
Format: Article
Language:English
Published: International Union of Crystallography 2011-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811035422
id doaj-aa8b76ed028e4ca589eaa69d3f53a53c
record_format Article
spelling doaj-aa8b76ed028e4ca589eaa69d3f53a53c2020-11-24T22:05:14ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-10-016710m1356m135610.1107/S1600536811035422Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)Giovanni PredieriClaudia GraiffLucio De LorentiisThe structure of the title compound, [Ph3P=N=PPh3]+[Ph3SnCl2]− or (C36H30NP2)[Sn(C6H5)3Cl2], obtained as a by product of the reaction between Ph3SnCl and [Ph3P=N=PPh3]+·HSeO3−, consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the SnIV atom in the anion. In the crystal, the ions interact only through a weak interaction between the Cl atom of the anion and an H atom of a phenyl ring of the cation.http://scripts.iucr.org/cgi-bin/paper?S1600536811035422
collection DOAJ
language English
format Article
sources DOAJ
author Giovanni Predieri
Claudia Graiff
Lucio De Lorentiis
spellingShingle Giovanni Predieri
Claudia Graiff
Lucio De Lorentiis
Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)
Acta Crystallographica Section E
author_facet Giovanni Predieri
Claudia Graiff
Lucio De Lorentiis
author_sort Giovanni Predieri
title Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)
title_short Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)
title_full Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)
title_fullStr Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)
title_full_unstemmed Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)
title_sort bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(iv)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-10-01
description The structure of the title compound, [Ph3P=N=PPh3]+[Ph3SnCl2]− or (C36H30NP2)[Sn(C6H5)3Cl2], obtained as a by product of the reaction between Ph3SnCl and [Ph3P=N=PPh3]+·HSeO3−, consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the SnIV atom in the anion. In the crystal, the ions interact only through a weak interaction between the Cl atom of the anion and an H atom of a phenyl ring of the cation.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811035422
work_keys_str_mv AT giovannipredieri bistriphenylphosphanylideneiminiumdichloridotriphenylstannateiv
AT claudiagraiff bistriphenylphosphanylideneiminiumdichloridotriphenylstannateiv
AT luciodelorentiis bistriphenylphosphanylideneiminiumdichloridotriphenylstannateiv
_version_ 1725826652057894912

Similar Items