Bis(triphenylphosphanylidene)iminium dichloridotriphenylstannate(IV)
The structure of the title compound, [Ph3P=N=PPh3]+[Ph3SnCl2]− or (C36H30NP2)[Sn(C6H5)3Cl2], obtained as a by product of the reaction between Ph3SnCl and [Ph3P=N=PPh3]+·HSeO3−, consists of discrete essentially isolated ions. Both the cation and the anion lie...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811035422 |
| Summary: | The structure of the title compound, [Ph3P=N=PPh3]+[Ph3SnCl2]− or (C36H30NP2)[Sn(C6H5)3Cl2], obtained as a by product of the reaction between Ph3SnCl and [Ph3P=N=PPh3]+·HSeO3−, consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the SnIV atom in the anion. In the crystal, the ions interact only through a weak interaction between the Cl atom of the anion and an H atom of a phenyl ring of the cation. |
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| ISSN: | 1600-5368 |