Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]

Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]

In the binuclear centrosymmetric crystal structure of the title compound, [Cu2(C7H14N5)2(C9H21P)2], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal–planar CuN2P coordination. Bond angles around the amino N atom sugg...

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Main Authors: Issam Kobrsi, Ghada Bassioni
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811022719
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spelling doaj-aa77a90a8aa54e9493916d1f877a7e332020-11-25T02:03:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m975m97610.1107/S1600536811022719Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]Issam KobrsiGhada BassioniIn the binuclear centrosymmetric crystal structure of the title compound, [Cu2(C7H14N5)2(C9H21P)2], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal–planar CuN2P coordination. Bond angles around the amino N atom suggest sp2 hybridization. Several intramolecular C—H...N interactions are present involving tetrazolate N atoms. http://scripts.iucr.org/cgi-bin/paper?S1600536811022719
collection DOAJ
language English
format Article
sources DOAJ
author Issam Kobrsi
Ghada Bassioni
spellingShingle Issam Kobrsi
Ghada Bassioni
Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]
Acta Crystallographica Section E
author_facet Issam Kobrsi
Ghada Bassioni
author_sort Issam Kobrsi
title Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]
title_short Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]
title_full Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]
title_fullStr Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]
title_full_unstemmed Bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2N2:N3)bis[(triisopropylphosphane)copper(I)]
title_sort bis(μ-5-diisopropylamino-1,2,3,4-tetrazolido-κ2n2:n3)bis[(triisopropylphosphane)copper(i)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description In the binuclear centrosymmetric crystal structure of the title compound, [Cu2(C7H14N5)2(C9H21P)2], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal–planar CuN2P coordination. Bond angles around the amino N atom suggest sp2 hybridization. Several intramolecular C—H...N interactions are present involving tetrazolate N atoms.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811022719
work_keys_str_mv AT issamkobrsi bisamp9565diisopropylamino1234tetrazolidoamp9542n2n3bistriisopropylphosphanecopperi
AT ghadabassioni bisamp9565diisopropylamino1234tetrazolidoamp9542n2n3bistriisopropylphosphanecopperi
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