N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide
In the title molecule, C21H32F2N3O2P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetrahedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with...
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International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811043029 |
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doaj-aa6bd13aef9e4cf2816887413a5dd6d22020-11-25T01:27:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-11-016711o3027o302710.1107/S1600536811043029N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamideMehrdad PourayoubiAtekeh TarahhomiArnold L. RheingoldJames A. GolenIn the title molecule, C21H32F2N3O2P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetrahedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with bond-angle sums of 358.4 and 357.0°) confirm their sp2 character. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generate R22(8) loops.http://scripts.iucr.org/cgi-bin/paper?S1600536811043029 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Mehrdad Pourayoubi Atekeh Tarahhomi Arnold L. Rheingold James A. Golen |
| spellingShingle |
Mehrdad Pourayoubi Atekeh Tarahhomi Arnold L. Rheingold James A. Golen N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide Acta Crystallographica Section E |
| author_facet |
Mehrdad Pourayoubi Atekeh Tarahhomi Arnold L. Rheingold James A. Golen |
| author_sort |
Mehrdad Pourayoubi |
| title |
N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide |
| title_short |
N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide |
| title_full |
N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide |
| title_fullStr |
N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide |
| title_full_unstemmed |
N,N′-Dicyclohexyl-N′′-(2,6-difluorobenzoyl)-N,N′-dimethylphosphoric triamide |
| title_sort |
n,n′-dicyclohexyl-n′′-(2,6-difluorobenzoyl)-n,n′-dimethylphosphoric triamide |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-11-01 |
| description |
In the title molecule, C21H32F2N3O2P, the P=O and N—H groups are syn with respect to each other, and the P atom is bonded in a distorted tetrahedral environment. The phosphoryl group adopts an anti orientation with respect to the carbonyl group. The angles at the tertiary N atoms (with bond-angle sums of 358.4 and 357.0°) confirm their sp2 character. In the crystal, inversion dimers linked by pairs of N—H...O hydrogen bonds generate R22(8) loops. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811043029 |
| work_keys_str_mv |
AT mehrdadpourayoubi nnamp8242dicyclohexylnamp8242amp824226difluorobenzoylnnamp8242dimethylphosphorictriamide AT atekehtarahhomi nnamp8242dicyclohexylnamp8242amp824226difluorobenzoylnnamp8242dimethylphosphorictriamide AT arnoldlrheingold nnamp8242dicyclohexylnamp8242amp824226difluorobenzoylnnamp8242dimethylphosphorictriamide AT jamesagolen nnamp8242dicyclohexylnamp8242amp824226difluorobenzoylnnamp8242dimethylphosphorictriamide |
| _version_ |
1725103388635430912 |