The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)

The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)

The title compound, Cd2P4O12, dicadmium cyclo-tetraphosphate, crystallizes isotypically with the members of the series MII2P4O12, where M = Mg, Mn, Fe, Co, Ni or Cu. Two CdO6 octahedra, one with 2 and one with overline{1} symmetry, share corners with the centrosymmetric P4O124− ring an...

Full description

Bibliographic Details
Main Author: Matthias Weil
Format: Article
Language:English
Published: International Union of Crystallography 2010-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810040195
id doaj-aa4f74445e07460e916f37479a430655
record_format Article
spelling doaj-aa4f74445e07460e916f37479a4306552020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611i75i7510.1107/S1600536810040195The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)Matthias WeilThe title compound, Cd2P4O12, dicadmium cyclo-tetraphosphate, crystallizes isotypically with the members of the series MII2P4O12, where M = Mg, Mn, Fe, Co, Ni or Cu. Two CdO6 octahedra, one with 2 and one with overline{1} symmetry, share corners with the centrosymmetric P4O124− ring anion that is built up from four corner-sharing PO4 tetrahedra. The isolated ring anions are arranged in layers parallel to (10overline{1}) with the CdO6 octahedra situated between these layers. The main difference between the individual MII2P4O12 structures pertains to the different sizes of the MO6 octahedra whereas the geometric parameters of all cyclo-P4O124− anions are very similar. http://scripts.iucr.org/cgi-bin/paper?S1600536810040195
collection DOAJ
language English
format Article
sources DOAJ
author Matthias Weil
spellingShingle Matthias Weil
The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)
Acta Crystallographica Section E
author_facet Matthias Weil
author_sort Matthias Weil
title The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)
title_short The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)
title_full The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)
title_fullStr The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)
title_full_unstemmed The cyclo-tetraphosphate Cd2P4O12, a member of the isotypic series M2P4O12 (M = Mg, Mn, Fe, Co, Ni, Cu)
title_sort cyclo-tetraphosphate cd2p4o12, a member of the isotypic series m2p4o12 (m = mg, mn, fe, co, ni, cu)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-11-01
description The title compound, Cd2P4O12, dicadmium cyclo-tetraphosphate, crystallizes isotypically with the members of the series MII2P4O12, where M = Mg, Mn, Fe, Co, Ni or Cu. Two CdO6 octahedra, one with 2 and one with overline{1} symmetry, share corners with the centrosymmetric P4O124− ring anion that is built up from four corner-sharing PO4 tetrahedra. The isolated ring anions are arranged in layers parallel to (10overline{1}) with the CdO6 octahedra situated between these layers. The main difference between the individual MII2P4O12 structures pertains to the different sizes of the MO6 octahedra whereas the geometric parameters of all cyclo-P4O124− anions are very similar.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810040195
work_keys_str_mv AT matthiasweil thecyclotetraphosphatecd2p4o12amemberoftheisotypicseriesm2p4o12mmgmnfeconicu
AT matthiasweil cyclotetraphosphatecd2p4o12amemberoftheisotypicseriesm2p4o12mmgmnfeconicu
_version_ 1725162866588254208

Similar Items