rac-2,2′-Bis(diphenylphosphanyl)-1,1′-binaphthyl: a racemic diphosphine ligand
The asymmetric unit of the title compound, C44H32P2, conventionally abbreviated BINAP, is one half of the complete chiral BINAP molecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the molecule in two identical halves; a center of symmetry between molecules...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812025603 |
| Summary: | The asymmetric unit of the title compound, C44H32P2, conventionally abbreviated BINAP, is one half of the complete chiral BINAP molecule, which adopts a C2 crystallographic point-group symmetry with a twofold axis splitting the molecule in two identical halves; a center of symmetry between molecules further determines the racemic pairs. There are no obvious supramolecular interactions between adjacent BINAP molecules. |
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| ISSN: | 1600-5368 |