Color-Tunable Organic Light Emitting Diodes for Deep Blue Emission by Regulating the Optical Micro-Cavity

• Main Authors: Jixin Jiang, Weiye Zheng, Junfei Chen, Zheng Xu, Dandan Song, Bo Qiao, Suling Zhao
• Format: Article
• Language: English
• Published: MDPI AG 2020-06-01
• Series: Molecules
• Subjects: micro-cavity; organic light emitting diodes; blue emission; spectral shift
• Online Access: https://www.mdpi.com/1420-3049/25/12/2867

Nowadays, most blue organic light emitting diodes (OLEDs) are fabricated by using sky-blue emitters which are more easily synthesized when compared with other deep blue emitters. Herein, we put forward a new idea of using an optical micro-cavity based on metal electrodes to regulate electroluminance (EL) spectra of sky-blue organic light emitting diodes to obtain a saturated deep blue emission with a narrowed full-width at half-maximum (FWHM). First, we simulate micro-cavity OLEDs and find that the transmission of the anode plays an important role in the forward emission. Meanwhile, the optical path of micro-cavity OLEDs as well as the phase shifting from electrodes influence the EL spectra and induce the extra intensity enhancement. The results show that when the resonant cavity optical path is regulated by changing the thickness of emitting layer (EML) from 25 nm to 75 nm in the micro-cavity, the EL peak of blue OLEDs has a redshift from 479 nm to 493 nm with FWHM shifting from 69.8 nm to 83.2 nm, when compared to the device without the micro-cavity, whose approximate EL peak and FWHM are 487 nm and 87 nm, respectively. However, the efficiency of electroluminescence decreases in micro-cavity OLEDs. We speculate that this is on account of the ohmic contact between ITO and Ag, the surface plasma effect and the rough morphology induced by Ag electrodes.