Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate

Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate

The title compound, [Co(C10H8N2)3][Fe(C2O4)3]·H2O, consists of two discrete tris(chelate) metal ions (CoIIIN6 and FeIIIO6 chromophores) and a water molecule. The structure is highly symmetrical; the CoIII and FeIII ions occupy positions with site symmetry 3.2. The coordination polyhedra...

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Main Authors: Oleg V. Shishkin, Irina V. Omelchenko, Volodymyr N. Kokozay, Eduard N. Chygorin, Svitlana R. Petrusenko
Format: Article
Language:English
Published: International Union of Crystallography 2012-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812003224
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spelling doaj-a9c4dc87ff6941419188ea48e831e6692020-11-25T01:08:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-03-01683m233m23410.1107/S1600536812003224Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrateOleg V. ShishkinIrina V. OmelchenkoVolodymyr N. KokozayEduard N. ChygorinSvitlana R. PetrusenkoThe title compound, [Co(C10H8N2)3][Fe(C2O4)3]·H2O, consists of two discrete tris(chelate) metal ions (CoIIIN6 and FeIIIO6 chromophores) and a water molecule. The structure is highly symmetrical; the CoIII and FeIII ions occupy positions with site symmetry 3.2. The coordination polyhedra of the metal atoms have a nearly octahedral geometry with noticeable trigonal distortions. The Co—N and Fe—O bond lengths are equal by symmetry, viz. 1.981 (2) and 1.998 (4) Å, respectively. The cations and anions are arranged alternately along their threefold rotation axes parallel to [001], forming chains that are packed in a hexagonal manner. The water molecules occupy voids between the chains. The crystal under investigation was an inversion twin.http://scripts.iucr.org/cgi-bin/paper?S1600536812003224
collection DOAJ
language English
format Article
sources DOAJ
author Oleg V. Shishkin
Irina V. Omelchenko
Volodymyr N. Kokozay
Eduard N. Chygorin
Svitlana R. Petrusenko
spellingShingle Oleg V. Shishkin
Irina V. Omelchenko
Volodymyr N. Kokozay
Eduard N. Chygorin
Svitlana R. Petrusenko
Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate
Acta Crystallographica Section E
author_facet Oleg V. Shishkin
Irina V. Omelchenko
Volodymyr N. Kokozay
Eduard N. Chygorin
Svitlana R. Petrusenko
author_sort Oleg V. Shishkin
title Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate
title_short Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate
title_full Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate
title_fullStr Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate
title_full_unstemmed Tris(2,2′-bipyridine-κ2N,N′)cobalt(III) tris(oxalato-κ2O1,O2)ferrate(III) monohydrate
title_sort tris(2,2′-bipyridine-κ2n,n′)cobalt(iii) tris(oxalato-κ2o1,o2)ferrate(iii) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-03-01
description The title compound, [Co(C10H8N2)3][Fe(C2O4)3]·H2O, consists of two discrete tris(chelate) metal ions (CoIIIN6 and FeIIIO6 chromophores) and a water molecule. The structure is highly symmetrical; the CoIII and FeIII ions occupy positions with site symmetry 3.2. The coordination polyhedra of the metal atoms have a nearly octahedral geometry with noticeable trigonal distortions. The Co—N and Fe—O bond lengths are equal by symmetry, viz. 1.981 (2) and 1.998 (4) Å, respectively. The cations and anions are arranged alternately along their threefold rotation axes parallel to [001], forming chains that are packed in a hexagonal manner. The water molecules occupy voids between the chains. The crystal under investigation was an inversion twin.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812003224
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AT irinavomelchenko tris22amp8242bipyridineamp9542nnamp8242cobaltiiitrisoxalatoamp9542o1o2ferrateiiimonohydrate
AT volodymyrnkokozay tris22amp8242bipyridineamp9542nnamp8242cobaltiiitrisoxalatoamp9542o1o2ferrateiiimonohydrate
AT eduardnchygorin tris22amp8242bipyridineamp9542nnamp8242cobaltiiitrisoxalatoamp9542o1o2ferrateiiimonohydrate
AT svitlanarpetrusenko tris22amp8242bipyridineamp9542nnamp8242cobaltiiitrisoxalatoamp9542o1o2ferrateiiimonohydrate
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