Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution

Phase diagram of (1−x)Na0.5K0.5NbO3–x(Bi0.5Na0.5)ZrO3 solid solution has been established from dielectric constant measurements and structure analyses. It is found that with increasing x, the C–T phase transition temperature TC−T and the T–O phase transition temperature TT−O decrease, while the O−R...

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Main Authors: Ruiping Wang, Mitsuru Itoh
Format: Article
Language:English
Published: World Scientific Publishing 2016-06-01
Series:Journal of Advanced Dielectrics
Subjects:
Online Access:http://www.worldscientific.com/doi/pdf/10.1142/S2010135X16500144
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spelling doaj-a973dbd062b74334b81f97b0b62a5bad2020-11-25T02:40:28ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682016-06-01621650014-11650014-510.1142/S2010135X1650014410.1142/S2010135X16500144Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solutionRuiping Wang0Mitsuru Itoh1National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568, JapanMaterials & Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori, Yokohama 226-8503, JapanPhase diagram of (1−x)Na0.5K0.5NbO3–x(Bi0.5Na0.5)ZrO3 solid solution has been established from dielectric constant measurements and structure analyses. It is found that with increasing x, the C–T phase transition temperature TC−T and the T–O phase transition temperature TT−O decrease, while the O−R phase transition temperature TO−R increases. TT−O of NKN–xBNZ is much different from that of NKN–xBZ solid solution. The result could be mainly elucidated by the hybridization between the A-site ion and oxygen.http://www.worldscientific.com/doi/pdf/10.1142/S2010135X16500144Lead-freepiezoelectricniobatephase transition
collection DOAJ
language English
format Article
sources DOAJ
author Ruiping Wang
Mitsuru Itoh
spellingShingle Ruiping Wang
Mitsuru Itoh
Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution
Journal of Advanced Dielectrics
Lead-free
piezoelectric
niobate
phase transition
author_facet Ruiping Wang
Mitsuru Itoh
author_sort Ruiping Wang
title Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution
title_short Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution
title_full Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution
title_fullStr Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution
title_full_unstemmed Phase diagram of (Na0.5K0.5)NbO3-(Bi0.5Na0.5)ZrO3 solid solution
title_sort phase diagram of (na0.5k0.5)nbo3-(bi0.5na0.5)zro3 solid solution
publisher World Scientific Publishing
series Journal of Advanced Dielectrics
issn 2010-135X
2010-1368
publishDate 2016-06-01
description Phase diagram of (1−x)Na0.5K0.5NbO3–x(Bi0.5Na0.5)ZrO3 solid solution has been established from dielectric constant measurements and structure analyses. It is found that with increasing x, the C–T phase transition temperature TC−T and the T–O phase transition temperature TT−O decrease, while the O−R phase transition temperature TO−R increases. TT−O of NKN–xBNZ is much different from that of NKN–xBZ solid solution. The result could be mainly elucidated by the hybridization between the A-site ion and oxygen.
topic Lead-free
piezoelectric
niobate
phase transition
url http://www.worldscientific.com/doi/pdf/10.1142/S2010135X16500144
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AT mitsuruitoh phasediagramofna05k05nbo3bi05na05zro3solidsolution
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