catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]

catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]

In the title complex, {[Cu(C11H16N4)2(H2O)2](C10H6O6S2)}n, the CuII atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent CuII atoms are linked by two bii...

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Main Authors: Lai-Ping Zhang, Shu-Tang Wen, Xiao-Ning Fu
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812045679
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spelling doaj-a96193d868c144ca843a7d3d6cabe1e92020-11-24T21:20:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1505m150510.1107/S1600536812045679catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]Lai-Ping ZhangShu-Tang WenXiao-Ning FuIn the title complex, {[Cu(C11H16N4)2(H2O)2](C10H6O6S2)}n, the CuII atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent CuII atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Intermolecular O—H...O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11).http://scripts.iucr.org/cgi-bin/paper?S1600536812045679
collection DOAJ
language English
format Article
sources DOAJ
author Lai-Ping Zhang
Shu-Tang Wen
Xiao-Ning Fu
spellingShingle Lai-Ping Zhang
Shu-Tang Wen
Xiao-Ning Fu
catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]
Acta Crystallographica Section E
author_facet Lai-Ping Zhang
Shu-Tang Wen
Xiao-Ning Fu
author_sort Lai-Ping Zhang
title catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]
title_short catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]
title_full catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]
title_fullStr catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]
title_full_unstemmed catena-Poly[[[diaquacopper(II)]-bis[μ-1,5-bis(1H-imidazol-1-yl)pentane-κ2N3:N3′]] naphthalene-1,5-disulfonate]
title_sort catena-poly[[[diaquacopper(ii)]-bis[μ-1,5-bis(1h-imidazol-1-yl)pentane-κ2n3:n3′]] naphthalene-1,5-disulfonate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description In the title complex, {[Cu(C11H16N4)2(H2O)2](C10H6O6S2)}n, the CuII atom, lying on an inversion center, is six-coordinated by two water molecules and four N atoms from four 1,5-bis(1H-imidazol-1-yl)pentane (biim-5) ligands in a distorted octahedral geometry. Adjacent CuII atoms are linked by two biim-5 ligands, forming a chain along [111]. Two atoms of the pentane group are disordered over two sets of sites, with an occupancy ratio of 0.554 (18):0.446 (18). Intermolecular O—H...O hydrogen bonds link the chains and the centrosymmetric naphthalene-1,5-disulfonate anions into a layer structure parallel to (0-11).
url http://scripts.iucr.org/cgi-bin/paper?S1600536812045679
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AT shutangwen catenapolydiaquacopperiibisamp95615bis1himidazol1ylpentaneamp9542n3n3amp8242naphthalene15disulfonate
AT xiaoningfu catenapolydiaquacopperiibisamp95615bis1himidazol1ylpentaneamp9542n3n3amp8242naphthalene15disulfonate
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