Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)

Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)

In the title compound, [Pt(C17H19N4)Cl], the PtII cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazolylidene) anion and coordinated by a Cl− anion in a distorted square-planar coordination geometry. π...

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Main Authors: Kui-Juan Peng, Zi-Xing Wang, Wen Wan
Format: Article
Language:English
Published: International Union of Crystallography 2013-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813006545
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spelling doaj-a8b81f885d5847dfacb497b1d406d40d2020-11-25T01:10:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694m218m21810.1107/S1600536813006545Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)Kui-Juan PengZi-Xing WangWen WanIn the title compound, [Pt(C17H19N4)Cl], the PtII cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazolylidene) anion and coordinated by a Cl− anion in a distorted square-planar coordination geometry. π–π stacking is observed between nearly parallel imidazole and benzene rings of adjacent molecules, the centroid–centroid distance being 3.802 (4) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536813006545
collection DOAJ
language English
format Article
sources DOAJ
author Kui-Juan Peng
Zi-Xing Wang
Wen Wan
spellingShingle Kui-Juan Peng
Zi-Xing Wang
Wen Wan
Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)
Acta Crystallographica Section E
author_facet Kui-Juan Peng
Zi-Xing Wang
Wen Wan
author_sort Kui-Juan Peng
title Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)
title_short Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)
title_full Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)
title_fullStr Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)
title_full_unstemmed Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)
title_sort chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1h-imidazol-2-ylidene)]platinum(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-04-01
description In the title compound, [Pt(C17H19N4)Cl], the PtII cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazolylidene) anion and coordinated by a Cl− anion in a distorted square-planar coordination geometry. π–π stacking is observed between nearly parallel imidazole and benzene rings of adjacent molecules, the centroid–centroid distance being 3.802 (4) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813006545
work_keys_str_mv AT kuijuanpeng chlorido1182425methyl13phenylenebis35dimethyl1himidazol2ylideneplatinumii
AT zixingwang chlorido1182425methyl13phenylenebis35dimethyl1himidazol2ylideneplatinumii
AT wenwan chlorido1182425methyl13phenylenebis35dimethyl1himidazol2ylideneplatinumii
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