Chlorido[1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazol-2-ylidene)]platinum(II)
In the title compound, [Pt(C17H19N4)Cl], the PtII cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazolylidene) anion and coordinated by a Cl− anion in a distorted square-planar coordination geometry. π...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813006545 |
| Summary: | In the title compound, [Pt(C17H19N4)Cl], the PtII cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenylene)bis(3,5-dimethyl-1H-imidazolylidene) anion and coordinated by a Cl− anion in a distorted square-planar coordination geometry. π–π stacking is observed between nearly parallel imidazole and benzene rings of adjacent molecules, the centroid–centroid distance being 3.802 (4) Å. |
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| ISSN: | 1600-5368 |