Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate
In the title dinuclear complex, [Cu2(C14H20ClN4O)ClO]·3H2O, one CuII cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both CuII cations are N,N′,O-chelated by one arm of the 2,6-bis[(2-aminoeth...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681202301X |
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doaj-a8907197519f42f2aa4606c480015fb12020-11-25T00:49:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m794m79510.1107/S160053681202301XChlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrateJing-Jing ZhouWei XiaoJia-Wei MaoHong ZhouIn the title dinuclear complex, [Cu2(C14H20ClN4O)ClO]·3H2O, one CuII cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both CuII cations are N,N′,O-chelated by one arm of the 2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolate anion, and one oxide anion bridges the two CuII cations, forming a dinuclear complex. One of the CuII cations is further coordinated by an Cl− anion in the apical direction. In the crystal, lattice water molecules are linked with the complex molecule via O—H...Cl hydrogen bonds while O—H...O hydrogen bonding occurs between lattice water molecules , forming three-dimensional network structure.http://scripts.iucr.org/cgi-bin/paper?S160053681202301X |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Jing-Jing Zhou Wei Xiao Jia-Wei Mao Hong Zhou |
| spellingShingle |
Jing-Jing Zhou Wei Xiao Jia-Wei Mao Hong Zhou Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate Acta Crystallographica Section E |
| author_facet |
Jing-Jing Zhou Wei Xiao Jia-Wei Mao Hong Zhou |
| author_sort |
Jing-Jing Zhou |
| title |
Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
| title_short |
Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
| title_full |
Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
| title_fullStr |
Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
| title_full_unstemmed |
Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate |
| title_sort |
chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(ii) trihydrate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-06-01 |
| description |
In the title dinuclear complex, [Cu2(C14H20ClN4O)ClO]·3H2O, one CuII cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both CuII cations are N,N′,O-chelated by one arm of the 2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolate anion, and one oxide anion bridges the two CuII cations, forming a dinuclear complex. One of the CuII cations is further coordinated by an Cl− anion in the apical direction. In the crystal, lattice water molecules are linked with the complex molecule via O—H...Cl hydrogen bonds while O—H...O hydrogen bonding occurs between lattice water molecules , forming three-dimensional network structure. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S160053681202301X |
| work_keys_str_mv |
AT jingjingzhou chloridoamp95626bis2aminoethyliminomethyl4chlorophenolatoamp956oxidodicopperiitrihydrate AT weixiao chloridoamp95626bis2aminoethyliminomethyl4chlorophenolatoamp956oxidodicopperiitrihydrate AT jiaweimao chloridoamp95626bis2aminoethyliminomethyl4chlorophenolatoamp956oxidodicopperiitrihydrate AT hongzhou chloridoamp95626bis2aminoethyliminomethyl4chlorophenolatoamp956oxidodicopperiitrihydrate |
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1725251532534841344 |