Bis(2-aminopyrazine-κN4)dichloridozinc

Bis(2-aminopyrazine-κN4)dichloridozinc

In the title adduct, [ZnCl2(C4H5N3)2], the ZnII atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-aminopyrazine ligand to the other; the coordination geometry is a distorted tetrahedron. In the crystal, adjacent molecules are linked by N—H...N...

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Main Authors: Shan Gao, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811026031
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spelling doaj-a7a21659512e4fbc80a913a6c8e929602020-11-24T21:32:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-08-01678m1049m105010.1107/S1600536811026031Bis(2-aminopyrazine-κN4)dichloridozincShan GaoSeik Weng NgIn the title adduct, [ZnCl2(C4H5N3)2], the ZnII atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-aminopyrazine ligand to the other; the coordination geometry is a distorted tetrahedron. In the crystal, adjacent molecules are linked by N—H...N hydrogen bonds across the center of inversion, generating a chain; neighboring chains are linked by N—H...Cl hydrogen bonds, forming a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811026031
collection DOAJ
language English
format Article
sources DOAJ
author Shan Gao
Seik Weng Ng
spellingShingle Shan Gao
Seik Weng Ng
Bis(2-aminopyrazine-κN4)dichloridozinc
Acta Crystallographica Section E
author_facet Shan Gao
Seik Weng Ng
author_sort Shan Gao
title Bis(2-aminopyrazine-κN4)dichloridozinc
title_short Bis(2-aminopyrazine-κN4)dichloridozinc
title_full Bis(2-aminopyrazine-κN4)dichloridozinc
title_fullStr Bis(2-aminopyrazine-κN4)dichloridozinc
title_full_unstemmed Bis(2-aminopyrazine-κN4)dichloridozinc
title_sort bis(2-aminopyrazine-κn4)dichloridozinc
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-08-01
description In the title adduct, [ZnCl2(C4H5N3)2], the ZnII atom lies on a twofold rotation axis that relates one Cl atom to the other as well as one 2-aminopyrazine ligand to the other; the coordination geometry is a distorted tetrahedron. In the crystal, adjacent molecules are linked by N—H...N hydrogen bonds across the center of inversion, generating a chain; neighboring chains are linked by N—H...Cl hydrogen bonds, forming a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811026031
work_keys_str_mv AT shangao bis2aminopyrazineamp954n4dichloridozinc
AT seikwengng bis2aminopyrazineamp954n4dichloridozinc
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