2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole

In the title molecule, C25H15BrN2S, the phenanthrene system is slightly skewed, with a dihedral angle of 8.94 (16)° between the outer benzene rings. The imidazole ring makes dihedral angles of 15.18 (16), 2.94 (15) and 88.46 (16)°, respectively, with the thiophene ring, the central benzene ring of t...

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Main Authors:	T. Kavitha, Sivakalai Mayakrishnan, T. Paramasivam Perumal, Chandramouleeswaran Suvasini, Srinivasakannan Lakshmi
Format:	Article
Language:	English
Published:	International Union of Crystallography 2017-01-01
Series:	IUCrData
Subjects:	crystal structure phenanthrene imidazole thiophene C—H...N and C—H...Br hydrogen bonding C—H...π interactions
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S241431461700089X

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spelling	doaj-a75efd289a434d15bb92113a4c9865232020-11-25T00:06:42ZengInternational Union of CrystallographyIUCrData2414-31462017-01-0121x17008910.1107/S241431461700089Xsu41242-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazoleT. Kavitha0Sivakalai Mayakrishnan1T. Paramasivam Perumal2Chandramouleeswaran Suvasini3Srinivasakannan Lakshmi4Research Department of Physics, S.D.N.B. Vaishnav College for Women, Chrompet, Chennai 600 044, IndiaOrganic & Bioorganic Chemistry, CSIR–Central Leather Research Institute, Adyar, Chennai 600 020, IndiaOrganic & Bioorganic Chemistry, CSIR–Central Leather Research Institute, Adyar, Chennai 600 020, IndiaResearch Department of Physics, S.D.N.B. Vaishnav College for Women, Chrompet, Chennai 600 044, IndiaResearch Department of Physics, S.D.N.B. Vaishnav College for Women, Chrompet, Chennai 600 044, IndiaIn the title molecule, C25H15BrN2S, the phenanthrene system is slightly skewed, with a dihedral angle of 8.94 (16)° between the outer benzene rings. The imidazole ring makes dihedral angles of 15.18 (16), 2.94 (15) and 88.46 (16)°, respectively, with the thiophene ring, the central benzene ring of the phenanthrene unit and the phenyl ring attached to the latter unit. In the molecule, there are two C—H...π interactions present involving the phenyl ring. In the crystal, molecules are linked by C—H...N and C—H...Br hydrogen bonds, forming zigzag chains along the a axis. The chains are linked by C—H...π interactions, forming a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S241431461700089Xcrystal structurephenanthreneimidazolethiopheneC—H...N and C—H...Br hydrogen bondingC—H...π interactions
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	T. Kavitha Sivakalai Mayakrishnan T. Paramasivam Perumal Chandramouleeswaran Suvasini Srinivasakannan Lakshmi
spellingShingle	T. Kavitha Sivakalai Mayakrishnan T. Paramasivam Perumal Chandramouleeswaran Suvasini Srinivasakannan Lakshmi 2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole IUCrData crystal structure phenanthrene imidazole thiophene C—H...N and C—H...Br hydrogen bonding C—H...π interactions
author_facet	T. Kavitha Sivakalai Mayakrishnan T. Paramasivam Perumal Chandramouleeswaran Suvasini Srinivasakannan Lakshmi
author_sort	T. Kavitha
title	2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole
title_short	2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole
title_full	2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole
title_fullStr	2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole
title_full_unstemmed	2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole
title_sort	2-(5-bromothiophen-2-yl)-1-phenyl-1h-phenanthro[9,10-d]imidazole
publisher	International Union of Crystallography
series	IUCrData
issn	2414-3146
publishDate	2017-01-01
description	In the title molecule, C25H15BrN2S, the phenanthrene system is slightly skewed, with a dihedral angle of 8.94 (16)° between the outer benzene rings. The imidazole ring makes dihedral angles of 15.18 (16), 2.94 (15) and 88.46 (16)°, respectively, with the thiophene ring, the central benzene ring of the phenanthrene unit and the phenyl ring attached to the latter unit. In the molecule, there are two C—H...π interactions present involving the phenyl ring. In the crystal, molecules are linked by C—H...N and C—H...Br hydrogen bonds, forming zigzag chains along the a axis. The chains are linked by C—H...π interactions, forming a three-dimensional supramolecular structure.
topic	crystal structure phenanthrene imidazole thiophene C—H...N and C—H...Br hydrogen bonding C—H...π interactions
url	http://scripts.iucr.org/cgi-bin/paper?S241431461700089X
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2-(5-Bromothiophen-2-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole

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