Chromatographic study of the organic matter from Moroccan Rif bituminous rocks

• Main Authors: Khalihena Groune, Mohammed Halim, Laurent Lemée, Mohammed Benmakhlouf, André Amblès
• Format: Article
• Language: English
• Published: Elsevier 2019-11-01
• Series: Arabian Journal of Chemistry
• Online Access: http://www.sciencedirect.com/science/article/pii/S1878535214002317

The bituminous rocks of the Upper Cretaceous in the Moroccan Rif have been assessed and characterized in detail using organic geochemical techniques and a variety of organic geochemical parameters. The organic matter from 4 sites was studied in order to determine its thermal maturity and its depositional environments. The organic extracts (bitumens) were fractionated on silica-potassium hydroxide column according to the aliphatic hydrocarbons, acid compounds and polar compounds. Aliphatic hydrocarbons were identified by gas chromatography and mass spectrometry (GC/MS).The distribution of the aliphatic hydrocarbon fractions, and the various organic geochemical parameters (pristane/phytane, isoprenoids/n-alkanes, CPI, C27:C28:C29 regular, C2920S/(20S+20R), C29ββ/(ββ+αα), C29/C30 hopanes and Ts/Tm) showed that the studied samples were generally mature. Two of the 4 samples appeared to be derived from source rocks deposited under anoxic conditions while suboxic to oxic conditions seemed to have been dominant for the remaining two samples. Rock–Eval pyrolysis data in addition to GC results suggested types II, III and IV kerogens for the studied samples. Keywords: Chromatography, Hydrocarbons, Biomarkers, Rock Eval pyrolysis, Bituminous rocks, Moroccan Rif