Dichloridotetrakis(1H-1,2,4-triazole-κN4)copper(II)

Dichloridotetrakis(1H-1,2,4-triazole-κN4)copper(II)

The central CuII atom of the molecular title complex, [CuCl2(C2H3N3)4], is situated on a site with symmetry 2.22. It is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four N atoms of four 1,2,4-triazole ligands and the axial positions occupied by two Cl ato...

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Bibliographic Details
Main Authors: Maja Vidmar, Tatjana Kobal, Bojan Kozlevčar, Primož Šegedin, Amalija Golobič
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812008872
Description
Summary:The central CuII atom of the molecular title complex, [CuCl2(C2H3N3)4], is situated on a site with symmetry 2.22. It is six-coordinated in an elongated octahedral geometry, with the equatorial plane defined by four N atoms of four 1,2,4-triazole ligands and the axial positions occupied by two Cl atoms situated on a twofold axis. The molecules are connected via N—H...Cl hydrogen bonds and the crystal consists of two interpenetrating three-dimensional hydrogen-bonded frameworks.
ISSN:1600-5368

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