Direct measurement of the oceanic carbon monoxide flux by eddy correlation

This report presents results from a field trial of ship-based air–sea flux measurements of carbon monoxide (CO) by direct eddy correlation with an infrared-laser trace gas analyzer. The analyzer utilizes Off-Axis Integrated-Cavity-Output Spectroscopy (OA-ICOS) to achieve high selectivity for CO, rap...

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Bibliographic Details
Main Authors: B. W. Blomquist, C. W. Fairall, B. J. Huebert, S. T. Wilson
Format: Article
Language:English
Published: Copernicus Publications 2012-12-01
Series:Atmospheric Measurement Techniques
Online Access:http://www.atmos-meas-tech.net/5/3069/2012/amt-5-3069-2012.pdf
Description
Summary:This report presents results from a field trial of ship-based air–sea flux measurements of carbon monoxide (CO) by direct eddy correlation with an infrared-laser trace gas analyzer. The analyzer utilizes Off-Axis Integrated-Cavity-Output Spectroscopy (OA-ICOS) to achieve high selectivity for CO, rapid response (~2 Hz) and low noise. Over a two-day sea trial, peak daytime seawater CO concentrations were ~1.5 nM and wind speeds were consistently 10–12 m s<sup>−1</sup>. A clear diel cycle in CO flux with an early afternoon maximum was observed. An analysis of flux error suggests the effects of non-stationarity are important, and air–sea CO flux measurements are best performed in regions remote from continental pollution sources.
ISSN:1867-1381
1867-8548