Construction of a hierarchical multiscale conducting network for enhanced thermoelectric response in organic PEDOT:PSS based nanocomposites

• Main Authors: Yong Zhang, Siqi Liu, J. Justin Koh, Chaobin He
• Format: Article
• Language: English
• Published: Elsevier 2021-01-01
• Series: Journal of Materiomics
• Subjects: PEDOT:PSS; Thermoelectrics; Energy harvesting; Hierarchical structure; Seebeck coefficient
• Online Access: http://www.sciencedirect.com/science/article/pii/S2352847820302215

Thermoelectric technology, which is characterized by the interconversion between heat and electricity, is demonstrated as an efficient and environmentally friendly route for thermal energy harvesting and solid-state cooling devices. The pursuit for high-performance room temperature thermoelectric materials is of significant interest. Here, we proposed a design strategy to dramatically improve the thermoelectric response by constructing a hierarchical multiscale conductor network (AgNWs/CNT) in polymer matrix (PEDOT:PSS). At the optimized composition, the highest Seebeck coefficient and electrical conductivity of base treated ternary PEDOT:PSS/AgNWs/CNT composite are optimized to be 58.6 μV K−1 and ∼1950 S cm−1. Correspondingly, the power factor is thus calculated to be on the order of 670 μW m−1 K−2, which is among one of the highest values compared with previous reports. The underlying mechanism is illustrated based on detailed structure, morphology and electron transport quantification. This work affords a novel strategy for the future development of high-performance room temperature nanocomposite thermoelectrics.