Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]

Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]

The title compound, C21H9F10N3, represents a potential redox non-innocent pyridine diimine ligand system. It consists of a central pyridine ring with two pentafluorophenyl substituted imine groups in positions 2 and 6. The whole molecule is generated by mirror symmetry, the mirror bisecting the N an...

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Main Authors: Jenna Boyle, Catherine Breakfield, Leah Buck, Catherine McMahon, Dominic C. Babbini
Format: Article
Language:English
Published: International Union of Crystallography 2017-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
pyridine diimine
redox non-innocent ligand
electron-withdrawing groups
Schiff base
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017008040
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spelling doaj-a572df9a5c8f47d6aeeb9f29ee7d53f22020-11-24T22:31:10ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-07-0173795495610.1107/S2056989017008040su5374Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]Jenna Boyle0Catherine Breakfield1Leah Buck2Catherine McMahon3Dominic C. Babbini4Department of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USADepartment of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USADepartment of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USADepartment of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USADepartment of Chemistry and Physics, Saint Mary's College, Notre Dame, IN 46556, USAThe title compound, C21H9F10N3, represents a potential redox non-innocent pyridine diimine ligand system. It consists of a central pyridine ring with two pentafluorophenyl substituted imine groups in positions 2 and 6. The whole molecule is generated by mirror symmetry, the mirror bisecting the N and para-C atom of the pyridine ring. The perfluorophenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, molecules stack along the a axis, but there are no significant intermolecular interactions present.http://scripts.iucr.org/cgi-bin/paper?S2056989017008040crystal structurepyridine diimineredox non-innocent ligandelectron-withdrawing groupsSchiff base
collection DOAJ
language English
format Article
sources DOAJ
author Jenna Boyle
Catherine Breakfield
Leah Buck
Catherine McMahon
Dominic C. Babbini
spellingShingle Jenna Boyle
Catherine Breakfield
Leah Buck
Catherine McMahon
Dominic C. Babbini
Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
pyridine diimine
redox non-innocent ligand
electron-withdrawing groups
Schiff base
author_facet Jenna Boyle
Catherine Breakfield
Leah Buck
Catherine McMahon
Dominic C. Babbini
author_sort Jenna Boyle
title Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]
title_short Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]
title_full Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]
title_fullStr Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]
title_full_unstemmed Crystal structure of (1E,1′E)-1,1′-(pyridine-2,6-diyl)bis[N-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]
title_sort crystal structure of (1e,1′e)-1,1′-(pyridine-2,6-diyl)bis[n-(2,3,4,5,6-pentafluorophenyl)ethan-1-imine]
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2017-07-01
description The title compound, C21H9F10N3, represents a potential redox non-innocent pyridine diimine ligand system. It consists of a central pyridine ring with two pentafluorophenyl substituted imine groups in positions 2 and 6. The whole molecule is generated by mirror symmetry, the mirror bisecting the N and para-C atom of the pyridine ring. The perfluorophenyl ring is inclined to the pyridine ring by 73.67 (8)°. In the crystal, molecules stack along the a axis, but there are no significant intermolecular interactions present.
topic crystal structure
pyridine diimine
redox non-innocent ligand
electron-withdrawing groups
Schiff base
url http://scripts.iucr.org/cgi-bin/paper?S2056989017008040
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AT catherinebreakfield crystalstructureof1e1e11pyridine26diylbisn23456pentafluorophenylethan1imine
AT leahbuck crystalstructureof1e1e11pyridine26diylbisn23456pentafluorophenylethan1imine
AT catherinemcmahon crystalstructureof1e1e11pyridine26diylbisn23456pentafluorophenylethan1imine
AT dominiccbabbini crystalstructureof1e1e11pyridine26diylbisn23456pentafluorophenylethan1imine
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