Synthesis and crystallographic characterization of a mononuclear cobalt(III) complex possessing both thiolate and thioether donors: reactivity of an thiolate-bridged pentanuclear Co2Ag3 complex with iodomethane
Treatment of an S-bridged pentanuclear AgI3CoIII2 complex, [Ag3{Co(L)}2]3+ [L3– = N(CH2NHCH2CH2S−)3], in which two tris(thiolate)-type mononuclear CoIII units ([Co(L)]) are bridged by three AgI ions through S atoms, with iodomethane (CH3I) gave a new CoIII mononuclear complex, [Co(LMe2)]2+ [LMe2− =...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2017-05-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989017005229 |