[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-κ3P,C1,P′](nitrato-κO)nickel(II)

The NiII atom in the title compound, [Ni(C24H43P2)(NO3)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating two positio...

Full description

Bibliographic Details
Main Authors: Brian J. Boro, Diane A. Dickie, Eileen N. Duesler, Karen I. Goldberg, Richard A. Kemp
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808032376
Description
Summary:The NiII atom in the title compound, [Ni(C24H43P2)(NO3)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement. The compound contains a twofold rotational axis with the nitrate group offset from this axis, except for an O atom of the nitrate group, generating two positions of 50% occupancy for the other atoms of the nitrate group.
ISSN:1600-5368