Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate

Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate

The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O—P...P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The AuI atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The molec...

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Bibliographic Details
Main Authors: Christina Taouss, Peter G. Jones
Format: Article
Language:English
Published: International Union of Crystallography 2016-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
gold
phosphine
chalcogenide
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016009816
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spelling doaj-a50c80443ea24277b2383ea06b08951d2020-11-25T00:59:09ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902016-07-017271006100810.1107/S2056989016009816pj2031Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvateChristina Taouss0Peter G. Jones1Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, GermanyInstitut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Postfach 3329, D-38023 Braunschweig, GermanyThe title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O—P...P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The AuI atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The molecules associate to form broad ribbons parallel to the c axis via two C—H...O, one C—H...Cl(Au) and one Au...Cl interaction.http://scripts.iucr.org/cgi-bin/paper?S2056989016009816crystal structuregoldphosphinechalcogenide
collection DOAJ
language English
format Article
sources DOAJ
author Christina Taouss
Peter G. Jones
spellingShingle Christina Taouss
Peter G. Jones
Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
gold
phosphine
chalcogenide
author_facet Christina Taouss
Peter G. Jones
author_sort Christina Taouss
title Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
title_short Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
title_full Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
title_fullStr Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
title_full_unstemmed Crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κS)-2-(diphenylphosphanoyl)ethene]gold(I) dichloromethane hemisolvate
title_sort crystal structure of chlorido[trans-1-(diphenylphosphanethioyl-κs)-2-(diphenylphosphanoyl)ethene]gold(i) dichloromethane hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2016-07-01
description The title compound, [AuCl(C26H22OP2S)]·0.5CH2Cl2, crystallizes with a trans-O—P...P—S geometry of the groups either side of the C=C double bond, which prevents any intramolecular contact between the Au and O atoms. The AuI atom exhibits a nearly linear coordination [Cl—Au—S = 177.55 (4)°]. The molecules associate to form broad ribbons parallel to the c axis via two C—H...O, one C—H...Cl(Au) and one Au...Cl interaction.
topic crystal structure
gold
phosphine
chalcogenide
url http://scripts.iucr.org/cgi-bin/paper?S2056989016009816
work_keys_str_mv AT christinataouss crystalstructureofchloridotrans1diphenylphosphanethioylks2diphenylphosphanoylethenegoldidichloromethanehemisolvate
AT petergjones crystalstructureofchloridotrans1diphenylphosphanethioylks2diphenylphosphanoylethenegoldidichloromethanehemisolvate
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